The reactions of the Cu(II)-nitrilotris(methylenephosphonic acid) complex with alkyl radicals in aqueous solutions (original) (raw)

Inorganica Chimica Acta, 2020

Abstract

Abstract The reactions of the radicals R, R = CH3 or CH2OH, with the complex CuII(ntp)(H2O) were studied. The kinetics of formation of the transient complexes (ntp)CuIII-R fit pseudo first order rate laws. The mechanism of decomposition of the transient complex (ntp)CuIII-CH3 at pH ≥ 7 involves homolysis of the CuIII-C bond. However, at pH

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