A second monoclinic polymorph of di-μ-chlorido-bis(chlorido{2-[(4-ethylphenyl)iminomethyl]pyridine-κ2N,N′}copper(II)) (original) (raw)

Abstract

A second monoclinic polymorph of di-lchlorido-bis(chlorido{2-[(4-ethylphenyl)iminomethyl]pyridine-j 2 N,N 0 0 0 }copper(II)

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References (19)

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  12. N2-Cu1-N1 80.94 (9) N2-C6-H6A 119.9 N2-Cu1-Cl2 94.43 (7) C5-C6-H6A 119.9 N1-Cu1-Cl2 119.40 (7) C12-C7-C8 119.1 (3) N2-Cu1-Cl1 171.55 (7) C12-C7-N2 119.5 (3) N1-Cu1-Cl1 93.80 (7) C8-C7-N2 121.4 (3)
  13. Cl2-Cu1-Cl1 93.91 (3) C9-C8-C7 119.7 (3) N2-Cu1-Cl1 i 90.23 (7) C9-C8-H8A 120.1 N1-Cu1-Cl1 i 113.66 (7) C7-C8-H8A 120.1 Cl2-Cu1-Cl1 i 126.81 (3) C8-C9-C10 122.0 (3) Cl1-Cu1-Cl1 i 85.82 (3) C8-C9-H9A 119.0 Cu1-Cl1-Cu1 i 94.18 (3) C10-C9-H9A 119.0 C1-N1-C5 118.0 (3) C11-C10-C9 117.5 (3) C1-N1-Cu1 130.8 (2) C11-C10-C13 121.8 (3) C5-N1-Cu1 111.22 (19) C9-C10-C13 120.7 (3) C6-N2-C7 119.9 (2) C10-C11-C12 121.3 (3) C6-N2-Cu1 112.36 (19) C10-C11-H11A 119.3 C7-N2-Cu1 127.69 (18) C12-C11-H11A 119.3 N1-C1-C2 122.4 (3) C7-C12-C11 120.3 (3) N1-C1-H1A 118.8 C7-C12-H12A 119.9 C2-C1-H1A 118.8 C11-C12-H12A
  14. Acta Cryst. (2012). E68, m920-m921 C3-C2-C1 119.5 (3) C14-C13-C10 113.4 (3) C3-C2-H2A 120.3 C14-C13-H13A 108.9 C1-C2-H2A 120.3 C10-C13-H13A 108.9 C2-C3-C4 118.6 (3) C14-C13-H13B 108.9 C2-C3-H3A 120.7 C10-C13-H13B 108.9 C4-C3-H3A 120.7 H13A-C13-H13B 107.7 C5-C4-C3 118.7 (3) C13-C14-H14A 109.5 C5-C4-H4A 120.7 C13-C14-H14B 109.5 C3-C4-H4A 120.7 H14A-C14-H14B 109.5 N1-C5-C4 122.8 (3) C13-C14-H14C 109.5 N1-C5-C6 115.0 (3) H14A-C14-H14C 109.5 C4-C5-C6 122.2 (3) H14B-C14-H14C 109.5 N2-C6-C5 120.3 (3)
  15. N2-Cu1-Cl1-Cu1 i 62.3 (5) Cu1-N1-C5-C4 -179.1 (2) N1-Cu1-Cl1-Cu1 i 113.48 (7) C1-N1-C5-C6 -179.5 (3) Cl2-Cu1-Cl1-Cu1 i -126.67 (3) Cu1-N1-C5-C6 2.2 (3) Cl1 i -Cu1-Cl1-Cu1 i 0.0 C3-C4-C5-N1 1.7 (5) N2-Cu1-N1-C1 178.7 (3) C3-C4-C5-C6 -179.7 (3) Cl2-Cu1-N1-C1 -91.4 (3) C7-N2-C6-C5 176.6 (3) Cl1-Cu1-N1-C1 5.3 (3) Cu1-N2-C6-C5 -4.4 (4) Cl1 i -Cu1-N1-C1 92.4 (3) N1-C5-C6-N2 1.5 (4) N2-Cu1-N1-C5 -3.39 (19) C4-C5-C6-N2 -177.3 (3) Cl2-Cu1-N1-C5 86.6 (2) C6-N2-C7-C12 168.0 (3) Cl1-Cu1-N1-C5 -176.73 (19) Cu1-N2-C7-C12 -10.8 (4) Cl1 i -Cu1-N1-C5 -89.63 (19) C6-N2-C7-C8 -12.8 (4) N1-Cu1-N2-C6 4.2 (2) Cu1-N2-C7-C8 168.4 (3) Cl2-Cu1-N2-C6 -114.9 (2) C12-C7-C8-C9 -2.7 (5) Cl1-Cu1-N2-C6 56.1 (6) N2-C7-C8-C9 178.1 (3) Cl1 i -Cu1-N2-C6 118.1 (2) C7-C8-C9-C10 0.1 (6) N1-Cu1-N2-C7 -176.9 (2) C8-C9-C10-C11 2.1 (6) Cl2-Cu1-N2-C7 64.0 (2) C8-C9-C10-C13 -178.3 (4) Cl1-Cu1-N2-C7 -125.0 (4) C9-C10-C11-C12 -1.8 (5) Cl1 i -Cu1-N2-C7 -63.0 (2) C13-C10-C11-C12 178.6 (3) C5-N1-C1-C2 -0.4 (4) C8-C7-C12-C11 2.9 (5) Cu1-N1-C1-C2 177.5 (2) N2-C7-C12-C11 -177.8 (3) N1-C1-C2-C3 0.6 (5) C10-C11-C12-C7 -0.7 (5) C1-C2-C3-C4 0.3 (5) C11-C10-C13-C14 123.0 (4) C2-C3-C4-C5 -1.4 (5) C9-C10-C13-C14 -56.6 (5) C1-N1-C5-C4 -0.8 (4) Symmetry code: (i) -x+1, -y+1, -z+1.
  16. Hydrogen-bond geometry (Å, º)
  17. D
  18. Acta Cryst. (2012). E68, m920-m921
  19. Symmetry codes: (ii) x+1, y, z; (iii) -x+1, y-1/2, -z+3/2.