Synthesis and characterization of low dimensional structure of carbon nanotubes (original) (raw)

An Overview of the Recent Progress in the Synthesis and Applications of Carbon Nanotubes

C

Carbon nanotubes (CNTs) are known as nano-architectured allotropes of carbon, having graphene sheets that are wrapped forming a cylindrical shape. Rolling of graphene sheets in different ways makes CNTs either metals or narrow-band semiconductors. Over the years, researchers have devoted much attention to understanding the intriguing properties CNTs. They exhibit some unusual properties like a high degree of stiffness, a large length-to-diameter ratio, and exceptional resilience, and for this reason, they are used in a variety of applications. These properties can be manipulated by controlling the diameter, chirality, wall nature, and length of CNTs which are in turn, synthesis procedure-dependent. In this review article, various synthesis methods for the production of CNTs are thoroughly elaborated. Several characterization methods are also described in the paper. The applications of CNTs in various technologically important fields are discussed in detail. Finally, future prospects...

Nanotechnology and nanostructured materials: trends in carbon nanotubes

Precision Engineering-journal of The International Societies for Precision Engineering and Nanotechnology, Vol. 28(1), pp. 16-30, 2004

Carbon nanotubes have attracted the attention of many researchers since their discovery last decade. These carbon molecules are tiny tubes with diameters down to 0.4 nm, while their lengths can grow up to a million times their diameter. Using their remarkable electrical properties, simple electronic logic circuits have been built. These structures are promising for the semiconductor industry which is leading the search for miniaturisation. They are not only very good conductors, but they also appear to be the yet found material with the biggest specific stiffness, having half the density of aluminium. This paper is written to give a consolidated view of the synthesis, the properties and applications of carbon nanotubes, with the aim of drawing attention to useful available information and to enhancing interest in this new highly advanced technological field for the researcher and the manufacturing engineer.

Carbon Nanotubes and Related Nanomaterials: Critical Advances and Challenges for Synthesis toward Mainstream Commercial Applications

ACS Nano

Advances in the synthesis and scalable manufacturing of single-walled carbon nanotubes (SWCNTs) remain critical to realizing many important commercial applications. Here we review recent breakthroughs in the synthesis of SWCNTs and highlight key ongoing research areas and challenges. A few key applications that capitalize on the properties of SWCNTs are also reviewed with respect to the recent synthesis breakthroughs and ways in which synthesis science can enable advances in these applications. While the primary focus of this review is on the science framework of SWCNT growth, we draw connections to mechanisms underlying the synthesis of other 1D and 2D materials such as boron nitride nanotubes and graphene.

Synthesis, Structure, and Properties of Single-Walled Carbon Nanotubes

Advanced Materials, 2009

Great interest in single-walled carbon nanotubes (SWCNTs) derives from their remarkable electrical, thermal, optical, and mechanical properties together with their lower density, which promise extensive and unique applications. Much progress has been achieved in the fundamental and applied investigations of SWCNTs over the past decade. At the same time, many obstacles still remain, hampering further development in this field. To clarify the emerging problems and to provide a comprehensive understanding of the field, we review the recent progress of research on the synthesis, structure, and properties of SWCNTs, in particular the SWCNT non-woven film, SWCNT rings, boron-nitrogen (B-N) co-doped SWCNTs (BCN-SWNTs), and individual SWCNTs. Some long-standing problems and topics warranting further investigations in the near future are addressed. Sishen Xie is a physicist and an academician at the Chinese Academy of Sciences (CAS) and a fellow of the Third World Academy of Sciences. He graduated in physics from Peking University in 1965 and received his PhD in 1983 from the Institute of Physics at CAS. His research interests are mainly in solid-state and materials physics, including high-T c superconductivity of oxides, phase diagrams and relations of inorganic systems, fullerenes, and nanomaterials.

Synthesis of Carbon Nanotubes

2005

Carbon nanotubes (CNTs) were discovered by S. Iijima, 3 who was looking for new carbon structures, in the deposit formed on graphite cathode surfaces during the electric-arc evaporation (or discharge) that is commonly employed to produce fullerene soot. The CNTs, also known as tubular fullerenes, are cylindrical graphene sheets of sp 2 bonded carbon atoms. These nanotubes are concentric graphitic cylinders closed at either end due to the presence of five-membered rings. The CNTs can be multiwalled with a central tube of nanometric diameter surrounded by graphitic layers separated by ~0.34nm [ ]. Unlike the multi-walled carbon nanotubes (MWNTs), in single-walled carbon nanotubes (SWNTs) there is only the tube and no graphitic layers i.e. SWNTs consist of singular graphene cylindrical walls. In 1999, Rode et al., 4,5 prepared a new form of carbon, a low-density cluster assembled carbon nanofoam. Carbon nanofoam has been prepared by a high-repetition-rate, high-power laser ablation of glassy carbon in Ar atmosphere. The nanofoam possesses a fractallike structure consisting of carbon clusters with an average diameter of 6-9 nm randomly interconnected into a web-like foam.The nanofoam is the first form of pure carbon to display ferromagnetism albeit temporary, at room temperature . 6 Ever since, the discovery of CNTs, several ways of preparing them has been explored. The CNTs have been synthesized by various methods e.g. electric arc discharge, laser evaporation and chemical vapor deposition. 7-9 These methods are very useful and are of widespread importance. The CNTs can be inert and can have a high aspect ratio, high tensile strength, low mass density, high heat conductivity, large surface area and versatile electronic behavior including high electron conductivity.

Carbon Nanotubes: Fabrication, Properties and Applications

Nausivios Chora, A Journal in Naval Science and Technology, Vol. 4, pp. 180-191, 2012

Carbon nanotubes are in the forefront of nanomaterials research since their discovery last decade. These carbon molecules are tiny tubes with diameters down to 0.4 nm, while their lengths can grow up to a million times their diameter. In this paper the most common fabrication methods for Carbon Nanotubes are explained and their remarkable properties are portrayed, namely mechanical, electrical and electronic properties. Finally, some applications of Carbon Nanotubes based on the aforementioned properties are discussed.

The wondrous world of carbon nanotubes: Structure, synthesis, properties and applications

2015

In this paper we review history, types, structure and different synthesis methods for carbon nanotubes (CNTs) including arc discharge, laser ablation & chemical vapor deposition. CNTs are hollow carbon structures with one or more walls, a small diameter on the nanometer scale and a large length in comparison. Because of their remarkable electronic and mechanical properties, they are unique and exciting and offer tremendous opportunities for the development of fundamentally new material systems. These cylindrical carbon molecules have novel properties that make them potentially useful in many applications in nanotechnology. Their unique surface area, stiffness, strength and resilience have led to much excitement in the field of pharmacy.