Magnetic aspects and assemblies of solvent-mediated layered manganese dicarboxylate based coordination polymers (original) (raw)

Polynuclear coordination complexes with manganese carboxylates have potential for advancing magnet technology due to their variable oxidation states and unique characteristics stemming from diverse carboxylate linkers. This research focuses on assembling high nuclear manganese clusters influenced by aromatic dicarboxylic acids in polar aprotic solvents to explore spin exchange interactions and structural design of new manganese carboxylate coordination polymers. The findings reveal the significant role of nonbonding interactions in determining assembly structures and their resulting antiferromagnetic properties.