Kinetics of monosubstitution reactions of phosphane-, arsine- and stibine-ligands with CO(CO)3NO (original) (raw)

Inorganica Chimica Acta, 1967

Giuseppe CardaciGiuseppe Cardaci

Abstract

... Following these results a kinetic mechanism has been proposed involving two competitive processes, first and secondorder respectively, the relative contribution of the secondorder process appearing to decrease in the order triphenylphosphine triphenylarsine triphenyl stibine. ...

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