Optical and radioluminescence properties of ZnO:Zn as a function of reduction degree and treatment temperature (original) (raw)

Journal of Applied Physics

Abstract

The aim of this work is to highlight the correlation between treatment conditions, composition, and structure of reduced zinc oxide (ZnO:Zn) with optical and radioluminescence properties for the production of high yield scintillating powders. Purchased zinc oxide (ZnO) powders (≈0.35 ± 0.15 μm) were thermally reduced in Ar/H2 (3%) atmosphere at temperatures ranging between 600 (≈0.40 ± 0.17 μm) and 1000 °C (≈6.4 ± 1.6 μm), obtaining ZnO:Zn powders. The reduction degree, evaluated through energy dispersive spectroscopy, showed a linear increase from 0% up to 20% (800 °C sample), reaching a plateau condition at about 25% for the highest treatment temperatures (1000 °C sample). Structural analysis highlighted the existence of a threshold temperature, previously reported in the literature, around 800 °C, beyond which (i) the grain size remarkably increases, (ii) the shape changes from hexagonal to round-shaped, and (iii) the intensity of electron spin resonance (ESR)-active defects at g...

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