The Exchange Fluctuation Theorem in Quantum Mechanics (original) (raw)
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Physical review. E, 2017
We investigate the statistics of heat exchange between a finite system coupled to reservoir(s). We have obtained analytical results for heat fluctuation theorems in the transient regime considering the Hamiltonian dynamics of the composite system consisting of the system of interest and the heat bath(s). The system of interest is driven by an external protocol. We first derive it in the context of a single heat bath. The result is in exact agreement with known result. We then generalize the treatment to two heat baths. We further extend the study to quantum systems and show that relations similar to the classical case hold in the quantum regime. For our study we invoke von Neumann two-point projective measurement in quantum mechanics in the transient regime. The study of quantum systems follows the same lines of argument as that of the classical system, and as a result the treatment used in the latter complements that used in the former. Our result is a generalization of Jarzynski-W...
Experimental verification of quantum heat exchange fluctuation relation
2018
We experimentally verify the Jarzynski and W\\"ojcik quantum heat exchange fluctuation relation by implementing the interferometric technique in liquid-state Nuclear Magnetic Resonance setup and study the exchange heat statistics between two weakly coupled spin-1/2 quantum systems. In presence of uncorrelated initial state with individual spins prepared in local Gibbs thermal states at different temperatures, the exchange fluctuation symmetry is verified for arbitrary transient time. In contrast, when the initial preparation includes correlation, the fluctuation symmetry breaks down and further leads to an apparent spontaneous flow of heat from cold to hot. Our experimental approach is general and can be systematically extended to study heat statistics for more complex out-of-equilibrium many-body quantum systems.
Quantum detailed balance conditions and fluctuation relations for thermalizing quantum dynamics
Physical Review E, 2018
Quantum detailed balance conditions and quantum fluctuation relations are two important concepts in the dynamics of open quantum systems: both concern how such systems behave when they thermalize because of interaction with an environment. We prove that for thermalizing quantum dynamics the quantum detailed balance conditions yield validity of a quantum fluctuation relation (where only forward-time dynamics is considered). This implies that to have such a quantum fluctuation relation (which in turn enables a precise formulation of the second law of thermodynamics for quantum systems) it suffices to fulfill the quantum detailed balance conditions. We, however, show that the converse is not necessarily true; indeed, there are cases of thermalizing dynamics which feature the quantum fluctuation relation without satisfying detailed balance. We illustrate our results with three examples.
Information fluctuation theorem for an open quantum bipartite system
We study an arbitrary nonequilibrium dynamics of a quantum bipartite system coupled to a reservoir. For its characterization, we present a fluctuation theorem (FT) that explicitly addresses the quantum correlation of subsystems during the thermodynamic evolution. To our aim, we designate the local and the global states altogether in the time-forward and the time-reversed transition probabilities. In view of the two-point measurement scheme, only the global states are subject to measurements whereas the local states are used only as an augmented information on the composite system. We specifically derive a FT in such a form that relates the entropy production of local systems in the time-forward transition to the change of quantum correlation in the time-reversed transition. This also leads to a useful thermodynamic inequality and we illustrate its advantage by an example of an isothermal process on Werner states.
Journal of physics, 1999
The behavior of the finite-temperature C-function, defined by Neto and Fradkin [Nucl. Phys. B 400, 525 (1993)], is analyzed within a d-dimensional exactly solvable lattice model, recently proposed by Vojta [Phys. Rev. B 53, 710 (1996)], which is of the same universality class as the quantum nonlinear O(n) sigma model in the limit n → ∞. The scaling functions of C for the cases d = 1 (absence of long-range order), d = 2 (existence of a quantum critical point), d = 4 (existence of a line of finite temperature critical points that ends up with a quantum critical point) are derived and analyzed. The locations of regions where C is monotonically increasing (which depend significantly on d) are exactly determined. The results are interpreted within the finite-size scaling theory that has to be modified for d = 4.
Role of quantum coherence in the thermodynamics of energy transfer
Physical Review E, 2018
Recent research on the thermodynamic arrow of time, at the microscopic scale, has questioned the universality of its direction. Theoretical studies showed that quantum correlations can be used to revert the natural heat flow (from the hot body to the cold one), posing an apparent challenge to the second law of thermodynamics. Such an "anomalous" heat current was observed in a recent experiment (arXiv:1711.03323), by employing two spin systems initially quantum correlated. Nevertheless, the precise relationship between this intriguing phenomenon and the initial conditions that allow it is not fully evident. Here, we address energy transfer in a wider perspective, identifying a nonclassical contribution that applies to the reversion of the heat flow as well as to more general forms of energy exchange. We derive three theorems that describe the energy transfer between two microscopic systems, for arbitrary initial bipartite states. Using these theorems, we obtain an analytical bound showing that certain type of quantum coherence can optimize such a process, outperforming incoherent states. This genuine quantum advantage is corroborated through a characterization of the energy transfer between two qubits. For this system, it is shown that a large enough amount of coherence is necessary and sufficient to revert the thermodynamic arrow of time. As a second crucial consequence of the presented theorems, we introduce a class of nonequilibrium states that only allow unidirectional energy flow. In this way, we broaden the set where the standard Clausius statement of the second law applies.
Journal of Physics A: Mathematical and General, 1999
The behavior of the finite-temperature C-function, defined by Neto and Fradkin [Nucl. Phys. B 400, 525 (1993)], is analyzed within a d-dimensional exactly solvable lattice model, recently proposed by Vojta [Phys. Rev. B 53, 710 (1996)], which is of the same universality class as the quantum nonlinear O(n) sigma model in the limit n → ∞. The scaling functions of C for the cases d = 1 (absence of long-range order), d = 2 (existence of a quantum critical point), d = 4 (existence of a line of finite temperature critical points that ends up with a quantum critical point) are derived and analyzed. The locations of regions where C is monotonically increasing (which depend significantly on d) are exactly determined. The results are interpreted within the finite-size scaling theory that has to be modified for d = 4.
The role of quantum coherence in the thermodynamics of energy transfer
Recent research on the thermodynamic arrow of time, at the microscopic scale, has questioned the universality of its direction. Theoretical studies showed that quantum correlations can be used to revert the natural heat flow (from the hot body to the cold one), posing an apparent challenge to the second law of thermodynamics. Such an " anomalous " heat current was observed in a recent experiment (arXiv:1711.03323), by employing two spin systems initially quantum correlated. Nevertheless, the precise relationship between this intriguing phenomenon and the initial conditions that allow it is not fully evident. Here, we address energy transfer in an extended perspective, identifying a nonclassical contribution that applies to the reversion of the heat flow as well as to more general forms of energy exchange. We derive three theorems that describe the energy transfer between two microscopic systems, for arbitrary initial bipartite states. Such a process can be optimized through a certain type of quantum coherence, outperforming incoherent states. We also introduce a class of nonequilibrium states that only allow unidirectional energy flow, thus broadening the set where the standard Clausius statement of the second law applies. Finally, we show that for two qubits, coherence boosts the energy transfer along any direction (direct or reverse). In this case, coherence is the quantum resource underpinning the reversion of the thermodynamic arrow of time.
Quantum Fluctuation Dissipation Theorem Revisited: Remarks and Contradictions
Fluctuation and Noise Letters, 2012
The quantum fluctuation dissipation theorem (QFDT) in the Callen–Welton [ Phys. Rev.83 (1951) 34] form is critically revisited. We show that the role of the system eigenvalues is in general not correctly accounted for by the accepted form of the QFDT. As a consequence, a series of quantum results claimed in the literature, like the presence of zero point fluctuations, the violation of the quantum regression hypothesis, the non-white spectrum of the Langevin force, etc. emerge as a consequence of an incorrect application of the theorem. In this context the case of the single harmonic oscillator is illustrated as a typical example where the accepted form of the QFDT is proven to fail.