M−P versus MM Bonds as Protonation Sites in the Organophosphide-Bridged Complexes [M 2 Cp 2 (μ-PR 2 )(μ-PR‘ 2 )(CO) 2 ], (M = Mo, W; R, R‘ = Ph, Et, Cy) † (original) (raw)

Abstract

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Organometallic compounds with multiple metal-metal bonds are important due to their high reactivity. This study explores protonation reactions of organophosphide-bridged complexes containing Mo and W, resulting in the formation of stable dimolybdenum complexes that exhibit agostic interactions. The research demonstrates that M-P bonds can compete with M-M bonds as protonation sites, offering new insights into the dynamics of these complexes and their reactivity.

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