Influence of localised surface plasmons on energy transfer between quantum dots (original) (raw)
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Proceedings of Spie the International Society For Optical Engineering, 2007
Förster resonant energy transfer (FRET) between the CdTe quantum dot (QD) acting as donors and acceptors is investigated at nanoscale proximity to gold nanoparticles (Au NPs). Photoluminescence (PL) studies of the acceptor QD emission from a mixed monolayer showed a distance dependent enhancement of the acceptor emission compared with that achieved for a donor-acceptor mixed monolayer in the absence of the Au NP layer. Time-resolved photoluminescence measurements showing a reduction in the donor lifetime, accompanied by an increase in the acceptor PL lifetime, provide further evidence for surface plasmon enhanced FRET.
Surface plasmon enhanced Förster resonance energy transfer between the CdTe quantum dots
Applied Physics Letters, 2008
Förster resonance energy transfer FRET between CdTe quantum dots QDs at nanoscale proximity to gold nanoparticle Au NP layers is investigated experimentally. We have observed the enhancement in the acceptor QDs' photoluminescence lifetime intensities. The decrease in donor QDs' exciton lifetime from 5.74 to 2.06 ns, accompanied by an increase in acceptor QDs' exciton lifetime from 3.38 to 7.52 ns, provided evidence for enhanced FRET between the QDs near Au NPs. The Au NPs' surface plasmon dipole fields are assisted to overcome the weak electronic coupling between the emitting donor and absorbing acceptor transition exciton dipoles in the homogeneous medium.
Nano Letters, 2011
Fluorescence resonant energy transfer ͑FRET͒ has been investigated between donor-acceptor pairs of type I CdSe/ZnS and type II CdSe/ZnTe quantum dots ͑QDs͒. An Au nanoparticles assisted FRET enhancement was clearly demonstrated. It is found that the efficiency of the energy transfer depends on the excitation wavelength and is largest when in resonance with the Au surface plasmon mode. With the large tunability of the emission intensity in near infrared region, our finding paves an excellent route for creating highly efficient optoelectronic devices and bioimaging labels derived from type II QDs.
Plasmonics: Metallic Nanostructures and Their Optical Properties V, 2007
Förster resonant energy transfer (FRET) between the CdTe quantum dot (QD) acting as donors and acceptors is investigated at nanoscale proximity to gold nanoparticles (Au NPs). Photoluminescence (PL) studies of the acceptor QD emission from a mixed monolayer showed a distance dependent enhancement of the acceptor emission compared with that achieved for a donor-acceptor mixed monolayer in the absence of the Au NP layer. Time-resolved photoluminescence measurements showing a reduction in the donor lifetime, accompanied by an increase in the acceptor PL lifetime, provide further evidence for surface plasmon enhanced FRET.
Energy transfer in monolayers of CdTe quantum dots (QDs), comprised of QDs of two different sizes, has been investigated. Förster resonant energy transfer (FRET) from QD donors to QD acceptors was observed and characterized using absorption and photoluminescence spectroscopy, as well as time-resolved photoluminescence measurements. A theory of FRET in two dimensions, taking into account random donor and acceptor distributions and exclusion zones around the donors, was used to fit the donor decays in mixed films. In this way the value of the Förster radius calculated from the spectral overlap was confirmed and a method for determining all important FRET parameters for QD monolayers from time-resolved photoluminescence measurements alone was found. The dependence of the measured FRET efficiency on the acceptor concentration can also be explained within this theory. Additionally, the rise in the acceptor emission enhancement for low acceptor:donor ratios indicates that energy is not only transferred from nearest neighbors but that donors at larger distances also contribute.
Physical Review B, 2011
The influences of donor and acceptor concentrations on Förster resonant energy transfer (FRET) in a separated donor / acceptor quantum dot bilayer structure have been investigated. Donor intra-ensemble energy transfer is shown to have an impact on the donor-acceptor FRET efficiency in the bilayer structure. At high donor concentrations the FRET distance dependence and the acceptor concentration dependence in the separated donor / acceptor layer structure agree well with theories developed for FRET between randomly distributed, homogeneous donor and acceptor ensembles. However, discrepancies between measurement and theory are found at low donor concentrations. A donor concentration study shows that the FRET efficiency decreases with increasing donor concentration even though a donor concentration-independent FRET efficiency is predicted by standard theory. The observed dependence of the FRET efficiency on the donor concentration can be explained within the FRET rate model, for a constant, donor-
Nanotechnology, 2017
Non-radiative energy transfer (NRET) can be an efficient process of benefit to many applications including photovoltaics, sensors, light emitting diodes and photodetectors. Combining the remarkable optical properties of quantum dots (QDs) with the electrical properties of quantum wells (QWs) allows for the formation of hybrid devices which can utilize NRET as a means of transferring absorbed optical energy from the QDs to the QW. Here we report on plasmon-enhanced NRET from semiconductor nanocrystal QDs to a QW. Ag nanoparticles in the form of colloids and ordered arrays are used to demonstrate plasmon-mediated NRET from QDs to QWs with varying top barrier thicknesses. Plasmon-mediated energy transfer (ET) efficiencies of up to ∼25% are observed with the Ag colloids. The distance dependence of the plasmon-mediated ET is found to follow the same d (-4) dependence as the direct QD to QW ET. There is also evidence for an increase in the characteristic distance of the interaction, thus ...
2010 12th International Conference on Transparent Optical Networks, 2010
The impact of intra-ensemble Förster resonant energy transfer (FRET) on the optical properties of monodispersed quantum dot (QD) monolayers and a donor/acceptor FRET bilayer structure are presented. The QD structures are characterized by steady-state absorption and photoluminescence (PL) spectroscopy as well as time-resolved PL measurements. The optical properties of the monodispersed monolayers, such as peak emission wavelength and PL decays, are strongly influenced by FRET from smaller to larger QDs within the ensemble. Comparing several QD samples, the spectral overlap of the QD ensemble and the QD concentration were identified as parameters that allow for tuning of FRET in monodispersed QD structures.
ACS Nano, 2012
Non-radiative energy transfer to metal nanoparticles is a technique used for optical based distance measurements which is often implemented in sensing. Both Förster resonant energy transfer (FRET) and nanometal surface energy transfer (NSET) mechanisms have been proposed for emission quenching in proximity to metal nanoparticles. Here quenching of emission of colloidal quantum dots in proximity to a monolayer of gold nanoparticles is investigated. Five differently sized CdTe quantum dots are used to probe the wavelength dependence of the quenching mechanism as their emission peak moves from on resonance to off resonance with respect to the localized surface plasmon peak of the gold nanoparticle layer. The gold nanoparticle concentration and distance dependences of energy transfer are discussed.
ACS Nano
The distance dependence of localized surface plasmon (LSP) coupled Förster resonance energy transfer (FRET) is experimentally and theoretically investigated using a trilayer structure composed of separated monolayers of donor and acceptor quantum dots with an intermediate Au nanoparticle layer. The dependence of the energy transfer efficiency, rate, and characteristic distance, as well as the enhancement of the acceptor emission, on the separations between the three constituent layers is examined. A d(-4) dependence of the energy transfer rate is observed for LSP-coupled FRET between the donor and acceptor planes with the increased energy transfer range described by an enhanced Förster radius. The conventional FRET rate also follows a d(-4) dependence in this geometry. The conditions under which this distance dependence is valid for LSP-coupled FRET are theoretically investigated. The influence of the placement of the intermediate Au NP is investigated, and it is shown that donor-pl...