Mild acetalisation of mono and dicarbonyl compounds catalysed by titanium tetrachloride. Facile synthesis of β-keto enol ethers (original) (raw)

Efficient acetalisation of aldehydes catalyzed by titanium tetrachloride in a basic medium

Angelo Clerici

Tetrahedron, 1998

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Alkylation of carbonyl compounds in the TiCl 4-promoted reaction of trimethylsilyl enol ethers with ethylene oxide † Dedicated to Professor Živorad Čeković, on the occasion of his 65th birthday. †

Zeljko Petrovski

Tetrahedron Letters, 2000

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The Reaction of Enol Ethers with Aldehydes Promoted by Titanium Tetraisopropoxide and Titanium Tetrachloride

Vishal Vaibhav Singh

Chemistry Letters, 1975

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Alkylation of carbonyl compounds in the TiCl4-promoted reaction of trimethylsilyl enol ethers with ethylene oxide

Zeljko Petrovski

Tetrahedron Letters - TETRAHEDRON LETT, 2000

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Asymmetric aldol reactions from titanium enolates of α-seleno ketones and esters

Luana Bagnoli

Tetrahedron: Asymmetry, 2004

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Asymmetric aldol reactions from titanium enolates of a-seleno ketones and esters

Luana Bagnoli

Tetrahedron Asymmetry, 2004

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1,4-syn-Asymmetric induction in the titanium-mediated aldol reactions of chiral methyl α-silyloxy ketones

Pedro Romea, F. Urpí

Tetrahedron Letters, 2010

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A Convenient Procedure for the Synthesis of Acetals from α-Halo Ketones

luis rodriguez

Advanced Synthesis & Catalysis, 2002

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1,4-Asymmetric induction in the titanium-mediated aldol reactions of α-benzyloxy methyl ketones

Pedro Romea

Tetrahedron Letters, 2008

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Alkylation of carbonyl compounds in the TiCl4-promoted reaction of trimethylsilyl enol ethers with epoxides

Zeljko Petrovski

Tetrahedron, 2001

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Highly Stereoselective Aldol Reaction Based on Titanium Enolates from ( S )-1-Benzyloxy-2-methyl-3-pentanone

F. Urpí

The Journal of Organic Chemistry, 2005

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First enantioselective addition of dialkylzinc to ketones promoted by titanium(IV) derivatives

Miguel Yus

Tetrahedron Letters, 1998

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Titanium tetrachloride promoted reaction of silyl ketene acetals with epoxides: a new method for the synthesis of γ-butanolides

Veselin Maslak

Tetrahedron Letters, 2002

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Catalytic asymmetric methallylation of ketones with an (H8-BINOLate)Ti-based catalyst

Patrick Walsh, Jeung Gon Kim

Organic letters, 2006

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Tetranuclear BINOL-Titanium Complex in Selective Direct Aldol Additions

Bernd Schetter

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Reduction of Aliphatic and Aromatic Cyclic Ketones to sec-Alcohols by Aqueous Titanium Trichloride/Ammonia System. Steric Course and Mechanistic Implications

Angelo Clerici

European Journal of Organic Chemistry, 2001

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Two-carbon homologation of ketones via sily ketene acetals: Synthesis of α,β-unsaturated acids and α-trimethylsilyl δ-ketoacids

Pierre Fromentin

Journal of Organometallic Chemistry, 2005

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Enantioselective Addition of Ketonitriles to Aldehydes Using A Titanium Complex

Christina Moberg

Synfacts, 2007

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Acylation of a transient Ti(IV)-enolate by acyl halides and anhydrides. Facile synthesis of α-hydroxy-β-ketoesters

Angelo Clerici

Tetrahedron, 1996

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TiCl 4 -promoted condensation of methyl acetoacetate, isobutyraldehyde, and indole: a theoretical and experimental study

Andrea Renzetti

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Different products in the reaction of the alcohols with cyclic and acyclic 1,3-dicarbonyl compounds: K5CoW12O40 as an electron transfer nano catalyst

Mohammad Joshaghani

Chinese Chemical Letters, 2012

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A highly effective aldol reaction mediated by Ti(O- n-Bu) 4/ t-BuOK combined reagent

Hiroshi Shinokubo

Tetrahedron Letters, 2000

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Supporting information: Highly Stereoselective Synthesis of syn-1,3-Diols through a Sequential Titanium-Mediated Aldol Reaction and LiBH4 Reduction

Pedro Romea

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Enantioselective ethylation of aromatic aldehydes catalysed by titanium(IV)–bis-BINOLate-2′,2″-propylether complexes: An inside view of the catalytic active species

Mariette M. Pereira

Journal of Molecular Catalysis A: Chemical, 2010

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Ti(IV)/BINOL-catalyzed asymmetric aldol reaction of a masked acetoacetic ester: pronounced influence of catalyst concentration on nonlinear effects

Margherita De Rosa

Tetrahedron Letters, 2003

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Stereoselective Decarboxylative Alkylation of Titanium(IV) Enolates with Diacyl Peroxides

Marina Pérez Palau

Organic Letters, 2019

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Enolate Formation from α-Iodoaldehydes and α-Iodoketones by Means of Allylsilane−Titanium Tetrachloride and Its Application to an Aldol Reaction

Hiroshi Shinokubo

Journal of Organic Chemistry, 1998

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PMA-SiO2 catalyzed synthesis of β-keto enol ethers

Sanjay Yadav

Chinese Chemical Letters, 2008

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Formation of Cyclic Ketals from Hydroxyalkyl Enol Ethers, a stereoelectronically controlledendo-trig-cyclization process

Yves Dory

Helvetica Chimica Acta, 1996

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Titanium chloride-mediated reactions of the silyl ketene acetals derived from N-methylephedrine esters: an asymmetric variant of the Mukaiyama reaction

Lino Colombo

The Journal of Organic Chemistry, 1987

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Overview of Organic Synthesis with Titanium(III)

Roxanne Spencer

1999

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