Unexpected features of stretched Si-H...Mo beta-agostic interactions (original) (raw)

Chemical communications (Cambridge, England), 2004

Abstract

Coupling of silanes with the imido group of (Ar'N)2Mo(PMe3)3 gives either the silanimine dimer (ArN-SiHCl)2 or Si-H agostic silylamido complexes which do not exhibit the commonly expected correlation between the nature of the substituents on silicon, the degree of Si-H addition and the value of the Si-H coupling constant.

Stanislav Ignatov hasn't uploaded this paper.

Let Stanislav know you want this paper to be uploaded.

Ask for this paper to be uploaded.