Synthesis of molybdenum imido alkylidene complexes and some reactions involving acyclic olefins (original) (raw)

Journal of The American Chemical Society, 1990

Abstract

The reaction between Mo(C-t-Bu)(dme)Clâ (dme = 1,2-dimethoxyethane) and MeâSiNHAr (Ar = 2,6-diisopropylphenyl) yields Mo(C-t-Bu)(NHAr)Clâ(dme) (1), which upon treatment with a catalytic amount of NEtâ is transformed into Mo(CH-t-Bu)(NAr)Clâ(dme) (2). Complexes of the type Mo(CH-t-Bu)(NAr)(OR)â (OR = OCMe(CFâ)â, OCMeâ(CFâ), O-t-Bu, or OAr) have been prepared from 2. Complexes of the type Mo(C-t-Bu)(NHAr)(OR)â (OR = OCMe(CFâ)â or OAr) have been prepared from

Richard Schrock hasn't uploaded this paper.

Let Richard know you want this paper to be uploaded.

Ask for this paper to be uploaded.