Stepwise syntheses of tri- and tetraphosphaporphyrinogens (original) (raw)

Stepwise syntheses of tri- and tetraphosphaporphyrinogens

Chemical Communications, 2012

Gilles Frison

Aurélie Escalle-lewis

Xavier Le Goff

Abstract

A double ring-expansion methodology allows the stepwise synthesis of tri- and tetra-phosphaporhyrinogens. Structural and calculational methods reveal extended delocalisation about their phospholide centres.

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