Elaboration and characterization of new conductive porous graphite membranes for electrochemical advanced oxidation processes (original) (raw)

Abstract

Three different graphite powders with different particles sizes were tested to synthesize tubular monochannel carbon supports for micro and ultrafiltration membranes using a new process. Carbon graphite powders and organic additives were mixed with an ethanolic solution of Resol s type phenolic resin. The extruded tubes were firstly consolidated by curing the resin at 150 1C then carbonized under nitrogen stream (1 mL min −1 ) for graphitization and pores opening.

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References (58)

  1. I.G. Laing, The impact of effluent regulations on the dyeing industry, Rev. Prog. Color. 21 (1991) 56-71.
  2. S.W. Oh, M.N. Kang, C.W. Cho, M.W. Lee, Detection of carcinogenic amines from dye stuffs or dyed substrates, Dyes Pigm. 33 (1997) 119-135.
  3. M. Faouzi, P. Canizares, A. Gadri, J. Lobato, B. Nasr, R. Paz, M.A. Rodrigo, C. Saez, Advanced oxidation processes for the treatment of wastes polluted with azoic dyes, Electrochim. Acta 52 (2006) 325-331.
  4. M.S. Lucas, J.A. Peres, Decolorization of the azo dye Reactive Black 5 by Fenton and photo-Fenton oxidation, Dyes Pigm. 71 (2006) 236-244.
  5. E. Rosales, M. Pazos, M.A. Longo, M.A. Sanromán, Electro-Fenton decoloration of dyes in a continuous reactor: a promising technology in colored wastewater treatment, Chem. Eng. J. 155 (2009) 62-67.
  6. Y. Fan, Z. Ai, L. Zhang, Design of an electro-Fenton system with a novel sandwich film cathode for wastewater treatment, J. Hazard. Mater. 176 (2010) 678-684.
  7. A. Da Pozza, P. Ferrantelli, C. Merli, E. Petrucci, Oxidation efficiency in the electro-Fenton process, J. Appl. Electrochem. 35 (2005) 391-398.
  8. S. Hammami, N. Oturan, N. Bellakhal, M. Dachraoui, M.A. Oturan, Oxidative degradation of direct orange 61 by electro-Fenton process using a carbon felt electrode: application of the experimental design methodology, J. Electroanal. Chem 610 (2007) 75-84.
  9. C. Flox, P.L. Cabot, F. Centellas, J.A. Garrido, R.M. Rodríguez, C. Arias, E. Brillas, Electrochemical combustion of herbicide mecoprop in aqueous medium using a flow reactor with a boron-doped diamond anode, Chemosphere 64 (2006) 892-902.
  10. I. Sires, N. Oturan, M.A. Oturan, R.M. Rodriguez, J.A. Garrido, E. Brillas, Electro-. Fenton degradation of antimicrobials triclosan and triclocarban, Electrochim. Acta 52 (2007) 5493-5503.
  11. A. Ozcan, Y. Sahin, A.S. Koparal, M.A. Oturan, Degradation of picloram by the electro-Fenton process, J. Hazard. Mater. 153 (2008) 718-727.
  12. N. Oturan, M.A. Oturan, Degradation of three pesticides used in viticulture by electrogenerated Fenton's reagent, Agron. Sustainable Dev. 25 (2005) 267-270.
  13. M. Panizza, G. Cerisola, Electro-Fenton degradation of synthetics dyes, Water Res. 43 (2009) 339-344.
  14. I. Sires, E. Guivarch, N. Oturan, M.A. Oturan, Efficient removal of triphenyl- methane dyes from aqueous medium by in situ electrogenerated Fenton's reagent at carbon-felt cathode, Chemosphere 72 (2008) 592-600.
  15. M. Panizza, G. Cerisola, Removal of organic pollutants from industrial wastewater by electrogenerated Fenton's reagent, Water Res. 35 (2001) 3987.
  16. J.E. Koresh, A. Soffer, The carbon molecular-sieve membranes-general prop- erties and the permeability of CH 4 /H 2 mixture, Sep. Sci. Technol 22 (1987) 973-978.
  17. CH. Liang, GY. Sha, SC. Guo, Carbon membrane for gas separation derived from coal tar pitch, Carbon 37 (1999) 1391-1397.
  18. J. Petersen, M. Matsuda, K. Haraya, Capillary carbon molecular sieve mem- branes derived from kapton for high temperature gas separation, J. Membr. Sci. 131 (1997) 85-94.
  19. LE. Sojo, A. Brocke, J. Fillion, SM. Price, Application of activated carbon membranes for on-line cleanup of vegetable and fruit extracts in the determination of pesticide multi residues by gas chromatography with mass selective detection, J. Chromatogr. 788 (1997) 141-154.
  20. W. Wei, H. Hu, L. You, G. Chen, Preparation of carbon molecular-sieve membrane from phenol-formaldehyde Novolac resin, Carbon 40 (2002) 445-467.
  21. TA. Centeno, AB. Fuertes, Supported carbon molecular-sieve membranes based on a phenolic resin, J. Membr. Sci. 160 (1999) 201-211.
  22. A. Soffer, J. Koresh, S. Saguee, Separation device, US Patent 4 (1987) 685-940.
  23. A. Soffer, M. Azariah, A. Amar, H. Cohen, D. Golub, S. Saguee, H. Tobias, Method of improving the selectivity of carbon membranes by chemical vapor deposi- tion, US Patent 5 (1997) 695-818.
  24. J. Hayashi, Y. Yamamoto, K. Kusakabe, S. Morooka, Simultaneous improvement of permeance and permselectivity of polyimide membrane by carbonization, Ind. Eng. Chem. Res. 34 (1995) 4364.
  25. J. Hayashi, H. Mizuta, Y. Yamamoto, K. Kusakabe, S. Morooka, Pore size control of carbonized BPDA-ODA polyimide membrane by chemical vapor deposition of carbon, J. Membr. Sci. 124 (1997) 243-251.
  26. H. Suda, K. Haraya, Gas permeation through micropores of carbon molecular sieve membranes derived from Kapton polyimide, J. Phys. Chem. B 101 (1997) 3988-3994.
  27. C.W. Jones, W.J. Koros, Carbon molecular sieve gas separation membranes. I. Preparation and characterization based on polyimide precursors, Carbon 32 (1994) 1419-1425.
  28. Y. Kusuki, H. Shimazaki, N. Tanihara, S. Nakanishi, T. Yoshinaga, Gas permea- tion properties and characterization of asymmetric carbon membranes pre- pared by asymmetric polyimide hollow fiber membrane, J. Membr. Sci. 134 (1997) 245-253.
  29. A.S. Damle, S.K. Gangwal, V.K. Venkataraman, Carbon membrane for gas separation: developmental studies, Gas Sep. Purif. 8 (1994) 137-147.
  30. K. Fukuyama, T. Nishizawa, K. Nishikawa, Effect of hot isostatic pressing on nanopore in glass-like carbon prepared from phenol-formaldehyde resin, Carbon 39 (2001) 1863-1867.
  31. N. Kasahara, S. Shiraishi, A. Oya, Heterogeneous graphitization of thin carbon fiber derived from phenol-formaldehyde resin, Carbon 41 (2002) 1645-1687.
  32. J. Górka, A. Zawislak, J. Choma, M. Jaroniec, KOH activation of mesoporous carbons obtained by soft-templating, Carbon 46 (2009) 1159-2274.
  33. M. Kubota, A. Hata, H. Matsuda, Preparation of activated carbon from phenolic resin by KOH chemical activation under microwave heating, Carbon 47 (2009) 2805-2811.
  34. I. Stamatin, A. Morozan, A. Dumitru, V. Ciupina, G. Prodan, J. Niewolski, H. Figiel, The synthesis of multi-walled carbon nanotubes (MWNTs) by catalytic pyrolysis of the phenol-formaldehyde resins, Physica E 37 (2007) 44-48.
  35. M.B. Rao, S. Sircar, C. Golden, Adsorbent membranes for gas separation, US Patent 5 (1992) 104-425.
  36. I. Jedidi, Elaboration de membranes inorganiques de filtration: application à la purification de solutions chimiques (Ph.D. thesis), University of Sfax, Tunisia, 2005.
  37. I. Jedidi, R. Ben Amar, A. Larbot, S. Khemakhem, A. Ben Salah, A. Charfi, C. Chtara, A. Fourati, N. Elloumi-Ammar et N. Abbes, Procédé d'élaboration de membranes de filtration en carbone, Brevet No: SN08394, Tunisia, 2009.
  38. N. Kishore, S. Sachan, K.N. Rai, A. Kumar, Synthesis and characterization of a nanofiltration carbon membrane derived from phenol-formaldehyde resin, Carbon 41 (2003) 2961-2972.
  39. W. Wei, G. Qin, H. Hu, L. You, G. Chen, Preparation of supported carbon molecular sieve membrane from Novolac phenol-formaldehyde resin, J. Membr. Sci. 303 (2007) 80-85.
  40. J.H. Clint, A.M. Lear, L.F. Oliver, S.R. Tennison, Membranes, Eur. Patent no. 0 474 424 (1991).
  41. F.K. Katsaros, T.A. Steriotis, A.K. Stubos, A. Mitropoulos, N.K. Kanellopoulos, S. R. Tennison, High pressure gas permeability of microporous carbon mem- branes, Microporous Mater. 8 (1997) 171-176.
  42. F.K. Katsaros, Th.A. Steriotis, G.E. Romanos, M. Konstantakou, Preparation and characterization of gas selective microporous carbon membranes, Micropor- ous and Mesoporous Mater. 99 (2007) 181-189.
  43. C. Song, T. Wang, Y. Pan, J. Qiu, Preparation of coal-based microfiltration carbon membrane and application in oily wastewater treatment, Sep. Purif. Technol. 51 (2006) 80-84.
  44. I. Jedidi, S. Khemakhem, A. Larbot, R. Amar, Elaboration and characterization of fly ash based mineral supports for microfiltration and ultrafiltration membranes, Ceram. Int. 35 (2009) 2747-2753.
  45. H.A. Mackay, The influence of polymer structure on the conversion of synthetic resins to carbon-coke, Carbon 8 (1970) 517-526.
  46. E. Fitzer, W. Schafer, The effect of crosslinking on the formation of glasslike carbons from thermosetting, Carbon 8 (1970) 353-364.
  47. S. Masmoudi, A. Larbot, H. El Feki, R. Ben Amar, Elaboration and properties of new ceramic microfiltration membranes from natural and synthesized apatite, Desalination 190 (2006) 89-103.
  48. A. Larbot, S. Alami-Younssi, M. Persin, J. Sarrazin, L. Cot, Preparation of a γ- alumina nanofiltration membrane, J. Membr. Sci. 97 (1994) 167-173.
  49. Y. Pan, W. Wang, T. Wang, P. Yao, Fabrication of carbon membrane and microfiltration of oil-in-water emulsion: an investigation on fouling mechan- isms, Sep. Purif. Technol. 57 (2007) 388-393.
  50. F. Tuinstra, J.L. Koening, Raman spectrum of graphite, J. Chem. Phys. 53 (1970) 1126-1131.
  51. S. Reich, C. Thomsen, Raman spectroscopy of graphite, Philos. Trans. R. Soc. London A 362 (2004) 2271-2288.
  52. Y. Wang, D.C. Alsmeyer, R.L. Mc Creery, Raman spectroscopy of carbon materials: structural basis of observed spectra, Chem. Mater. 2 (1990) 557-563.
  53. T.H. Ko, W.S. Kuo, Y.H. Chang, Raman study of the microstructure changes of phenolic resin during pyrolysis, Polym. Compos. 21 (2000) 745-750.
  54. D. Cottinet, P. Couderc, J.L Saint-Romain, P. Dhamelincourt, Raman microprobe study of heat-treated pitches, Carbon 26 (1988) 339-344.
  55. P.D. Green, C.A. Johnson, K.M. Thomas, Application of laser Raman microprobe spectroscopy to the characterization of coals and cokes, Fuel 62 (1983) 1013-1023.
  56. P. Lespade, A. Marchand, M. Couze, F. Gruege, Caractérisation de matériaux carbonés par microspectrométrie Raman, Carbon 22 (1984) 375-385.
  57. S. Hammami, N. Bellakhal, N. Oturan, M.A. Oturan, M. Dachraoui, Degradation of Acid Orange 7 by electrochemically generated 1OH radicals in acidic aqueous medium using boron-doped diamond or platinum anode: a mechan- istic study, Chemosphere 73 (2008) 678-684.
  58. C. Flox, S. Ammar, C. Arias, E Brillas, A.V Vargas-Zavala, R. Abdelhedi, Electro- Fenton and photoelectro-Fenton degradation of indigo carmine in acidic aqueous medium, Appl. Catal. B Environ. 67 (2006) 93-104.