Ab Initio Studies of [1,5]-H Shifts:  Pentadiene and Beyond (original) (raw)

The Journal of Organic Chemistry, 2000

Abstract

... The transition state, a Hückel (4n + 2) π-electron array, has the C s symmetry and a suprafacial topology predicted by Woodward and Hoffmann. 33 An IRC connects this transition state to the local minimum s-cis pentadiene. ... Woodward, RB; Hoffmann, R. Angew. Chem., Int. Ed. ...

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