Columnar Organization in Mesogenic cis - and trans -[MX 2 (C⋮NR) 2 ] Complexes (M = Pd, Pt) (original) (raw)

Chemistry of Materials, 1998

Abstract

Palladium and platinum (II) complexes [MX2 {C⋮ NC6H2 (3, 4, 5-OC n H2 n+ 1) 3} 2](X= Cl, Br, I; n= 4, 6, 8, 10, 12) have been prepared. The free isocyanides are not liquid crystals, but most of their complexes [MX2 {C⋮ NC6H2 (3, 4, 5-OC n H2 n+ 1) 3} 2](M= Pd, Pt; X= Cl, Br ...

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