Synthesis, Characterization, and Electrochemical Behavior of Mixed-Ligand Complexes of Cobalt(III) with Dimethylglyoxime and Some Amino Acids (original) (raw)

Synthesis and Reactivity in Inorganic Metal-organic and Nano-metal Chemistry, 2003

Abstract

The syntheses of non‐electrolyte complexes of the general formula [Co(Hdmg)2(HA)X], where Hdmg˭dimethylglyoximato monoanion, HA˭glycine (Gly), Serine (Ser), Cysteine (Cys) or Cystine (Cys–Cys) and X˭Cl, Br, I, SCN are described. The structure of the complexes proposed according to elemental analyses, IR, UV‐Visible and H NMR spectra is pseudo-octahedral. The cyclic voltammograms in DMSO at a GC disk electrode consist of two

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