Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework (original) (raw)
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Metal-organic frameworks (MOFs) are a fascinating class of porous crystalline materials constructed by organic ligands and inorganic connectors. Owing to their noteworthy catalytic chemistry, and matching or compatible coordination with numerous materials, MOFs offer potential applications in diverse fields such as catalysis, proton conduction, gas storage, drug delivery, sensing, separation and other related biotechnological and biomedical applications. Moreover, their designable structural topologies, high surface area, ultrahigh porosity, and tunable functionalities all make them excellent materials of interests for nanoscale applications. Herein, an effort has been to summarize the current advancement of MOF-based materials (i.e., pristine MOFs, MOF derivatives, or MOF composites) for electrocatalysis, photocatalysis, and biocatalysis. In the first part, we discussed the electrocatalytic behavior of various MOFs, such as oxidation and reduction candidates for different types of ...
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As a class of versatile porous materials, MOFs have shown enormous potential for adsorption for environmental remediation and fuel purification. To efficiently remove harmful gases, it is not sufficient to use MOFs of the appropriate size/shape of the pores, and other more specific interactions between harmful adsorbents and the host are desirable. Most of the harmful gases are highly reactive. The adsorption of these gases often degrades the porous structures of MOFs. However, much progress has been made in the last few years to develop very persistent organic frameworks. Certainly more and more fundamental studies will appear in this direction, which should enhance the practical application of this type of new porous material for air purification and related fields in the future. MOFs contain multiple functional groups, conjugate bonds, and metal ions that can help for understanding the interactions between MOFs and pollutants and hense increase the adsorption efficiency. MOFs suf...
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The pursuit of rapid development in the area of catalysis, solar energy, environmental remediation, wastewater treatment and other aspects of ecological and sustainable chemistry has prompted substantial research by material chemists, physicists, academics and other scientists for the development of porous material. A lot of energy had been invested in this course by scientist, research organizations and public sector agencies from antiquity, but the resulting solution has been somewhat undesirable until two decades ago when Metal-Organic Frameworks (MOFs) appears to offer a glimpse of solution to those challenging issues. The adaptability, flexibility, uniqueness and usability of the metal-organic frameworks material, and its suitability to every facet of scientific and technological advancement has since triggered an incredible upsurge in studies aimed at uncovering more of the inherent influential properties of the materials, and its improvement for the betterment of material science and research world. This review is aimed at investigating some of the recent advancements/ breakthrough in metal-organic frameworks, synthetic methodologies and impending applications
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