NaSc(BH 4 ) 4 : A Novel Scandium-Based Borohydride (original) (raw)

2010, The Journal of Physical Chemistry C

A new alkaline transition-metal borohydride, NaSc(BH 4 ) 4 , is presented. The compound has been studied using a combination of in situ synchrotron radiation powder X-ray diffraction, thermal analysis, and vibrational and NMR spectroscopy. NaSc(BH 4 ) 4 forms at ambient conditions in ball-milled mixtures of sodium borohydride and ScCl 3 . A new ternary chloride Na 3 ScCl 6 (P2 1 /n, a ) 6.7375(3) Å, b ) 7.1567(3) Å, c ) 9.9316(5) Å, ) 90.491(3)°, V ) 478.87(4) Å 3 ), isostructural to Na 3 TiCl 6 , was identified as an additional phase in all samples. This indicates that the formation of NaSc(BH 4 ) 4 differs from a simple metathesis reaction, and the highest scandium borohydride yield (22 wt %) was obtained with a reactant ratio of ScCl 3 /NaBH 4 of 1:2. NaSc(BH 4 ) 4 crystallizes in the orthorhombic crystal system with the space group symmetry Cmcm (a ) 8.170(2) Å, b ) 11.875(3) Å, c ) 9.018(2) Å, V ) 874.9(3) Å 3 ). The structure of NaSc(BH 4 ) 4 consists of isolated homoleptic scandium tetraborohydride anions, [Sc(BH 4 ) 4 ] -, located inside slightly distorted trigonal Na 6 prisms (each second prism is empty, triangular angles of 55.5 and 69.1°). The experimental results show that each Sc 3+ is tetrahedrally surrounded by four BH 4 tetrahedra with a 12-fold coordination of H to Sc, while Na + is surrounded by six BH 4 tetrahedra in a quite regular octahedral coordination with a (6 + 12)-fold coordination of H to Na. The packing of Na + cations and [Sc(BH 4 ) 4 ]anions in NaSc(BH 4 ) 4 is a deformation variant of the hexagonal NiAs structure type. NaSc(BH 4 ) 4 is stable from RT up to ∼410 K, where the compound melts and then releases hydrogen in two rapidly occurring steps between 440 and 490 K and 495 and 540 K. Thermal expansion of NaSc(BH 4 ) 4 between RT and 408 K is anisotropic, and lattice parameter b shows strong anomaly close to the melting temperature.