Electrosynthesis and study of some physical properties of conductive and solid-state gas sensing polydiphenylamine (original) (raw)

Abstract

Polydiphenylamine was prepared using electrochemical oxidation of the corresponding monomer diphenylamine in an acetonitrile solution containing sodium perchlorate (NaClO 4 ) and characterized spectroscopically. First, some physical characterization using infrared (FTIR) measurement shows that this material has a polymeric structure. Moreover, Differential Scanning Calorimetry (DSC) and thermal gravimetric analysis (TAG) showed a good stability at temperatures above 200 • C. Second, the electrical conductivity and dielectric properties of polydiphenylamine were studied as guides for sensing performance using impedance spectroscopy technique in the frequency range 5 Hz-13 MHz at various temperatures (118-150 • C).

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