Optical and structural investigation of InAs/AlSb/GaSb heterostructures (original) (raw)

We report on the growth and characterisation of non-intentionally doped InAs/AlSb strained multiple quantum wells (MQWs), grown on GaSb substrates by molecular beam epitaxy (MBE). The structural characterisation is performed using X-ray re¯ectometry (XRR) as a complementary tool to high resolution X-ray diraction (HRXRD) experiments. For the ®rst time in this material system, optical characterisation by photo-induced absorption spectroscopy have been carried out. A strong e 1 3 e 2 p-polarised intersubband absorption is observed with a full width at half maximum of 11 meV at 77 K, showing the good quality of the material. Ó

Electroluminescence in p-InAs/AlSb/InAsSb/AlSb/p(n)-GaSb type II heterostructures with deep quantum wells at the interface

Semiconductors, 2010

Luminescent characteristics of asymmetric p InAs/AlSb/InAsSb/AlSb/p GaSb type II hetero structures with deep quantum wells at the heterointerface are studied. The heterostructures were grown by metalorganic vapor phase epitaxy. Intense positive and negative luminescence was observed in the range of photon energies of 0.3-0.4 eV with a forward and reverse bias, respectively. Dependences of the spectra and intensities for positive and negative luminescence on the pumping current and on the temperature are studied in the range of 77-380 K. It is established that, at a temperature higher than 75°C, intensity of negative lumi nescence surpasses that of positive luminescence by 60%. The suggested heterostructures can be used as light emitting diodes (photodiodes) with switched positive and negative luminescence in the mid IR spectral range of 3-4 µm.

Growth of InAsSb/InAs MQWs on GaSb for mid-IR photodetector applications

Journal of Crystal Growth, 2009

We report the OMVPE growth and characterization of InAsSb/InAs strain balanced multiple quantum wells lattice-matched to GaSb substrates for potential application as mid-infrared detectors for wavelengths beyond 4 mm. Detailed transmission electron microscopy measurements were performed to evaluate the degree of Ga and Sb intermixing at the GaSb/InAsSb and InAs/InAsSb interfaces. Photoluminescence emission up to 5 mm was observed for superlattice structures with only 15% antimony. The dependence of PL on wavelength is red shifted compared to expectations based on type I band alignment.

Spatially direct and indirect photoluminescence from InAs/AlSb heterostructures

Physical Review B, 1994

We present a Fourier-transform photoluminescence study of InAs/AlSb type-II heterostructures, spanning the midinfrared 1-12-pm wavelength range. The investigated samples consist of single and double quantum wells, grown on GaAs substrates by molecular-beam epitaxy, with different buffer-layer structures for strain accommodation. The photoluminescence intensity is found to be very sensitive to the detailed structure of the underlying buffer sequence. The use of a GaSb buffer or a GaSb/AlSb superlattice in the buffer gives rise to an additional radiative-recombination channel in the near infrared, which competes with radiative recombination in the InAs quantum wells at longer wavelengths. Variations in the spectra observed under visible and infrared excitation provide evidence that the recently observed persistent photo effect is governed by hole capture in the GaSb layers in the buffer sequence. Furthermore, very wide quantum wells (100 and 200 nm) show spatially direct as well as spatially indirect photoluminescence, providing insight into the nature of the transition from the bulklike semiconductor to the type-II heterostructure.

Study of interfaces in GaInSb/InAs quantum wells by high-resolution X-ray diffraction and reciprocal space mapping

Journal of Crystal Growth, 1999

The electrical and optical properties of advanced epitaxial structures, such as quantum wells and superlattices are strongly influenced by the quality of their interfaces. The GaInSb/InAs system is particularly important because of its promise for use in infrared detection in the 8-14 mum ranges. In this material system the two compounds do not share a common anion, and different bond types exist at the interface depending upon the growth parameters. We have looked at single quantum-well structures grown with solid source molecular beam epitaxy such that a distinct interface type would be found in each sample. X-ray rocking curves and full dynamical simulations were performed for each quantum well structure. Quantum wells with three types of interfaces were grown and analyzed; random interfaces, Sb-like interfaces, and As-like interfaces formed with a one monolayer group III deposition followed by a five second group V soak. With the exception of the interfaces, all three SQWs have nominally the same structure; 5000 Å of GaSb buffer layer grown upon a GaSb substrate, a 150 Å quantum well with 35 Å Ga 0.75In 0.25Sb barriers and a final GaSb cap layer of 50 Å thickness. Well-resolved Pendellösung fringes were found in all samples indicating high quality in the epitaxial layers and interfaces. The SQW with the As-like interfaces had the highest degree of quality as evidenced by persistence of the fringes.

Magneto-infrared modes in InAs-AlSb-GaSb coupled quantum wells

Physical Review B, 2010

We have studied a series of InAs/GaSb coupled quantum wells using magneto-infrared spectroscopy for high magnetic fields up to 33 T within temperatures ranging from 4 K to 45 K in both Faraday and tilted field geometries. This type of coupled quantum wells consists of an electron layer in the InAs quantum well and a hole layer in the GaSb quantum well, forming the so-called two dimensional electron-hole bilayer system. Unlike the samples studied in the past, the hybridization of the electron and hole subbands in our samples is largely reduced by having narrower wells and an AlSb barrier layer interposed between the InAs and the GaSb quantum wells, rendering them weakly hybridized. Previous studies have revealed multiple absorption modes near the electron cyclotron resonance of the InAs layer in moderately and strongly hybridized samples, while only a single absorption mode was observed in the weakly hybridized samples. We have observed a pair of absorption modes occurring only at magnetic fields higher than 14 T, which exhibited several interesting phenomena. Among which we found two unique types of behavior that distinguishes this work from the ones reported in the literature. This pair of modes is very robust against rising thermal excitations and increasing magnetic fields alligned parallel to the heterostructures. While the previous results were aptly explained by the antilevel crossing gap due to the hybridization of the electron and hole wavefunctions, i.e. conduction-valence Landau level mixing, the unique features reported in this paper cannot be explained within the same concept. The unusual properties found in this study and their connection to the known models for InAs/GaSb heterostructures will be disccused; in addition, several alternative ideas will be proposed in this paper and it appears that a spontaneous phase separation can account for most of the observed features.

Molecular-beam epitaxy of InSb/GaSb quantum dots

(2007) Journal of Applied Physics, 101 (12), art. no. 124309, .

We have investigated the molecular-beam epitaxy (MBE) of InSb nanostructures on (100) GaSb substrates. We show that MBE leads to a low density (∼1-3× 109 cm-2) of large islands even when varying the growth conditions on a wide range (substrate temperature ∼370-450 °C, growth rate ∼0.3-1.2 MLs). Plastic relaxation takes place from the onset of island formation, regardless of the amount of InSb deposited after the two-dimensional to three-dimensional transition. These results show that In adatoms have a very long diffusion length on a Sb-terminated surface and that the energy for dislocation generation in InSb is low. This can be attributed to the low enthalpy of formation and low melting point of InSb. To circumvent this problem we have developed a MBE growth procedure based on the deposition of an amorphous InSb layer at low temperature followed by an annealing step to allow for reorganization to take place. This dramatic change of the growth conditions leads to the formation of small InSb quantum dots with a density in excess of 7× 1010 cm-2. Uncapped quantum dots, however, are relaxed. In contrast, buried quantum dots are fully strained and emit near 3.5 μm at room temperature. Our results show that although formerly similar the InSb/GaSb materials system behaves completely differently from the InAs/GaAs case study system.

Effects of As (2) Versus As (4) on InAs/GaSb Heterostructures: As-for-Sb Exchange and Film Stability

2001

We have used cross-sectional scanning tunneling microscopy and x-ray diffraction to characterize and compare the effects of As 2 versus As 4 on the growth of InAs/GaSb heterostructures by molecular beam epitaxy. When GaSb surfaces are exposed to an As 2 flux, the As exchanges with the surface Sb in an anion exchange reaction that creates layers of GaAs. In contrast, when GaSb surfaces are exposed to As 4 fluxes, there is no evidence of the As-for-Sb exchange reaction. When comparing the use of As 2 and As 4 in periodic InAs/GaSb superlattices, the differences in the As incorporation rate into GaSb is further evident in x-ray diffraction spectra as a shift in the average lattice constant of the epilayer due to GaAs bond formation. Although inhibiting the exchange reaction would be useful in the minimization of the cross incorporation of As in the GaSb layers, the growth of InAs/GaSb heterostructures using As 4 can be complicated by the introduction of film instabilities that have not been observed in growths using As 2 .

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