Photoselection and the structure of highly excited states : rotationally resolved spin-orbit autoionizations spectrum of HCl (original) (raw)

The Journal of Chemical Physics, 1991

Kenneth Haber

Edward Grant

Yang Jiang

Abstract

Ultraviolet two-photon photoselection, followed by visible one-photon absorption is applied to HCl to record the first double-resonant spin–orbit autoionization spectrum of a hydrogen halide, and the first rotationally resolved such spectrum of HCl. The J= 2 level of the F Δ (v ...

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