Effect of microporous layer on MacMullin number of carbon paper gas diffusion layer (original) (raw)
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Capillary pressures in carbon paper gas diffusion layers having hydrophilic and hydrophobic pores
International Journal of Heat and Mass Transfer, 2012
Capillary pressures in a carbon paper gas diffusion layer (GDL) having hydrophilic and hydrophobic pores of a polymer electrolyte membrane fuel cell (PEMFC) are investigated by both lattice Boltzmann simulations and experimental measurements. The simulated and measured capillary pressures as a function of water saturation for water drainage and imbibition processes in the GDL are presented and compared. It is shown that the pore-scale simulated drainage and imbibition capillary pressure curves are in good agreement with that obtained by experiment, both indicating the coexistence of hydrophilic and hydrophobic properties in the polytetrafluoroethylene (PTFE) treated carbon paper GDLs. The fitted capillary pressure curves, obtained from this paper, can provide more accurate predictions of the capillary pressure in carbon paper GDLs with non-uniform porosity and wettability than the standard Leverett-Udell relationship which was obtained for soil with more uniform porosity and wettability.
Correlation for the Effective Gas Diffusion Coefficient in Carbon Paper Diffusion Media
Energy & Fuels, 2009
The understanding of mass transport limitations in polymer electrolyte membrane (PEM) fuel cells is crucial in the research and progress of this technology. The structure of the components, specifically the as diffusion layer (GDL), of PEM fuel cells, is complex. Thus, for the purpose of simulating mass transport in the GDL, the effect of the structure on the diffusion coefficient is taken into account by introducing an effective diffusion coefficient. The effective diffusion coefficient of a gas is lower than its corresponding bulk diffusion coefficient due to the presence of a solid matrix in the porous materials. Currently, the Bruggeman approximation is the most widely used correlation for estimating the effective diffusion coefficient in the GDL. Other semiempirical models are also available. However, these correlations overestimate the effective diffusion coefficient due to the assumptions on which they are based. In this study, correlations for the through-plane and in-plane diffusibility in the GDL are developed based on a three-dimensional (3D) simulation of gas diffusion in the GDL. The 3D structure of the TORAY carbon paper with no binding material is reconstructed using stochastic models and used as the modeling domain. The numerical results are shown to have a good agreement with experimental data of diffusibility in both directions. Correlations for two different porosity ranges are given.
Single phase through-plane permeability of carbon paper gas diffusion layers
Journal of Power Sources, 2012
Effects of mechanical compression and PTFE content on the through-plane gas permeability of gas diffusion layers (GDLs) of PEM fuel cells are investigated both experimentally and theoretically. A new test bed is designed and built which allows pressure drop and air flow rate measurement for various GDL samples. The measured values are used to calculate the through-plane permeability. Various GDLs are obtained and tested over a wide range of PTFE content and compression ratio. The experimental data show a reverse relationship between the through-plane permeability and both PTFE content and mechanical compression. An existing model for through-plane permeability of planar fibrous structures is revisited to develop a model that accommodates effects of PTFE content and mechanical compression. The proposed model captures the trends of the experimental data for the through-plane permeability, measured in the present study or reported by others.
International Journal of Hydrogen Energy, 2014
Proton exchange membrane fuel cells Compressive stress on gas diffusion layer a b s t r a c t Gas diffusion layer (GDL) is subjected to compressive stress at high temperature along with polymer electrolyte membrane in the fabrication process and in assembling the fuel cell stacks. Compressive stress decreases the thickness of GDL, electrical conductivity, permeability, and affects the pores. Carbon cloth based GDL withstands higher strain level when compared to carbon paper and the pore structure is also disrupted to a greater extent in cloth based GDL. In the present paper, we have addressed the effects of stress on pore structure of cloth based GDL. An optimum GDL must offer low mass transport resistance in an operating PEM fuel cell. The pore size analysis of pristine GDL and GDLs pressed at different pressure levels (200, 600 & 1000 kg cm À2 ) and their characteristics are evaluated using capillary flow porometry. The compressive stress affects the three types of pores in GDL called bubble point pore, mean flow pore and smallest pore. The change in electrical resistance, wetting behavior and surface morphology is also examined as a function of compressive stress. The fuel cell performances using these GDLs pressed at different compressive stresses are also evaluated and presented. The highest PEMFC performance is achieved at a compressive stress of 200 kg cm À2 , which could be attributed to the combined effect of reduced ohmic resistance and optimized pore structure. The order of increasing performance in terms of current density is observed to be j 200 > j Pristine > j 600 > j 1000 at 0.15 V.
Journal of Electroanalytical Chemistry
Carbon Papers (CPs) have been widely used as a Gas Diffusion Layer (GDL) for high performance fuel cells. Herein we report a novel method for production of GDL, without the need to carbonization and graphitization steps that is common steps in GDL production. CP is provided by a dry-laying of carbon fibers (CFs) and expanded graphite (EG) in the phenolic resin and the composites are compared with carbon paper of Toray Co., Ltd. The effect of paper thickness, aspect ratio of CF and EG value of the composite are investigated. The characterizations are performed by scanning electron microscope, maximum pore size, mean pore size, permeability, electrical conductivity, flexibility, and performance (I-V) curve. The results shown that in the optimized state of the composition in the manufactured composite, the values of mean pore size, permeability, electrical conductivity, and performance curve is reasonable and near the Toray paper, however the manufactured composite show a much higher flexibility than that of Toray paper in a qualitative test. In addition, due to removing the graphitization and carbonization steps for production of carbon paper, the produced carbon paper costs are much lower than Toray paper.
Effect of a GDL based on carbon paper or carbon cloth on PEM fuel cell performance
2011
A commercially available GDL based on carbon paper or carbon cloth as a macroporous substrate was characterized by various physical and electrochemical measurements: mercury porosimetry, surface morphology analysis, contact angle measurement, water permeation measurement, polarization techniques, and ac-impedance spectroscopy. SGL 10BB based on carbon paper demonstrated dual pore size distribution and high water flow resistance owing to less permeable macroporous substrate, and more hydrophobic and compact microporous layer, as compared to ELAT-LT-1400 W based on carbon cloth. The membrane-electrode-assembly fabricated using SGL 10BB showed an improved fuel cell performance when air was used as an oxidant. The ac-impedance response indicated that a microporous layer which has high volume of micropores and more hydrophobic property allows oxygen to readily diffuse towards the catalyst layer due to effective water removal from the catalyst layer to the gas flow channel.
Elucidating differences between carbon paper and carbon cloth in polymer electrolyte fuel cells
Electrochimica Acta, 2007
This paper seeks to develop a structure-performance relationship for gas diffusion layers (GDLs) of polymer electrolyte fuel cells (PEFCs), and hence to explain the performance differences between carbon paper (CP) and carbon cloth (CC). Three-dimensional simulations, based on a two-phase model with GDL structural information taken into account, are carried out to explore the fundamentals behind experimentally observed performance differences of the two carbon substrates, i.e. CC and CP, under low-and high-humidity operations. Validation against polarization data is made under both operating conditions, and the results indicate that the CC is the better choice as a GDL material at high-humidity operations due to its low tortuosity of the pore structure and its rough textural surface facilitating droplet detachment. However, under dry conditions, the CP shows better performance due to its more tortuous structure, which prevents the loss of product water to dry gas streams, thus increasing the membrane hydration level and reducing the ohmic loss. The present work is one step toward developing a science-based framework for selection of materials for next-generation, high-performance gas diffusion media.
Journal of Power Sources, 2012
A gas diffusion layer (GDL) in a proton exchange membrane fuel cell may consist of several, materials of different porosities, with each material serving a specific set of functions. For example, samples analyzed in this work consisted of a macro porous carbon paper substrate treated with a, hydrophobic wet proofing material in differing amounts, which was then coupled to a micro porous, layer. The porosities of four such GDLs were determined by using 2D scanning electron microscope (SEM) images to mathematically model the volumes filled by each solid in the 3D structures. Results, were then compared with mercury intrusion porosimetry (MIP) measurements to verify the accuracy, of the method. It was found that the use of SEM not only allowed for detailed porosity analysis of, separate porous materials within the GDL, but also porosity for the entire GDL could be calculated for, the seemingly complex structures with reasonable accuracy. With some basic geometric assumptions, and use of the superposition principle, the calculated results were accurate to less than a 2% absolute, difference of the porosity measured by MIP for each of the four samples analyzed.
Journal of Power Sources, 2014
In-plane permeability of gas diffusion backing (GDB) of proton exchange membrane fuel cells (PEMFCs) was investigated experimentally. Toray-paper and SGL-paper were selected as GDB test samples. Several Toray-papers were treated in-house with polytetrafluoroethylene (PTFE) using the immersion technique, dried either under atmospheric or vacuum pressure, and then sintered. The dependence of PTFE distribution in the through-plane direction on the PTFE drying conditions was examined using scanning electron microscopy (SEM)-based energy dispersive X-ray spectroscopy (EDS) imaging. The EDS image maps revealed that the PTFE distribution strongly depended on the drying condition, and PTFE drying under vacuum pressure yielded a relatively uniform PTFE distribution. The measured in-plane permeability suggests that the homogeneous distribution of PTFE achieved by the vacuum drying produces a porosity-leveling effect. In addition, the relationship between the in-plane permeability and porosity of the Toray-paper samples followed the KozenyeCarman relation, whereas due to non-fibrous solids such as binder, that of the SGL-paper samples did not.