Effect of counterion size in spherical electric double layer of concave shape (original) (raw)

The IEEE Region 8 EUROCON 2003. Computer as a Tool., 2003

Abstract

The steric effect of counterions on the electrical properties of spherical electric double layer of concave shape is discussed. In the theory, the electrostatic interaction is described by the mean field approximation, while the finite size of particles in the solution is considered by the excluded volume effect. We showed that near the spherical charged surface of concave shape, the

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