Highly Regio and Stereospecific Palladium-Catalysed Allyation of Enolates from Ketones (original) (raw)

Countercation Effects in Palladium Catalysed Allylation of Enolates

Rob John

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Selective carbon-carbon bond formation via transition metal catalysis. 29. A highly regio- and stereospecific palladium-catalyzed allylation of enolates derived from ketones

sugata chatterjee

Journal of Organic Chemistry, 1982

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Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of β-ketoesters: An Unusual Counterion Effect

feijun wang

Angewandte Chemie International Edition, 2011

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Stereoselective palladium-catalyzed allylic alkylations of peptideamide enolates

Régis Guillot

Org. Biomol. Chem., 2011

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Allylic alcohols as synthetic enolate equivalents: Isomerisation and tandem reactions catalysed by transition metal complexes

Belén Matute

Dalton Transactions, 2012

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ChemInform Abstract: Palladium-Catalyzed Desulfinylative C-C Allylation of Grignard Reagents and Enolates Using Allylsulfonyl Chlorides and Esters

Srinivas Dubbaka, Chandra Volla

ChemInform, 2009

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Organic synthesis via enolates

Vimal Rarh

2008

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Alkylation of enolates from .beta.-dicarbonyl compounds with sulfonium salt electrophiles

michael garst

The Journal of Organic Chemistry, 1983

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Expanding the scope of the indium-promoted allylation reaction: 4-(bromomethyl)-1,3-dioxol-2-one as a synthetic equivalent of a 3-arylhydroxyacetone enolate

Miljan Bigovic

Tetrahedron Letters, 2013

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Surprisingly Mild “Enolate-Counterion-Free” Pd(0)-Catalyzed Intramolecular Allylic Alkylations

Peter Fristrup

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Dual Palladium- and Proline-Catalyzed Allylic Alkylation of Enolizable Ketones and Aldehydes with Allylic Alcohols

Bernhard Breit

Organic Letters, 2009

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Enantioselective Generation and Diastereoselective Reactions of Chiral Enolates Derived from ?-Heterosubstituted Carboxylic Acids. Preliminary Communication

Reto Naef

Helvetica Chimica Acta, 1981

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Enantioselective Conjugate Allylation of Cyclic Enones

Douglass Taber

The Journal of Organic Chemistry, 2011

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Catalytic Enantioselective Addition of Allylic Organometallic Reagents to Aldehydes and Ketones

Nur Amalina

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Direct palladium-catalyzed allylic alkylations of alcohols with enamines: Synthesis of homoallyl ketones

Farhat REZGUI

Tetrahedron Letters, 2017

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Regio- and stereoselective palladium(0)-catalyzed alkylation of vinyloxiranes with non-stabilized lithium ester enolates nucleophiles. A direct access to highly functionalized allylic alcohols

Maryse Elliott

Tetrahedron Letters, 1998

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Palladium-catalyzed intramolecular allylic alkylation of α-sulfinyl carbanions: a new asymmetric route to enantiopure γ-lactams

Giovanni Poli

Tetrahedron Letters, 2010

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Catalytic asymmetric allylation of ketones and a tandem asymmetric allylation/diastereoselective epoxidation of cyclic enones

Jeung Gon Kim

Journal of the …, 2004

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Stereocontrol during the alkylation of enolates attached to .pi.-allyl-Mo(CO)2Cp systems

Wiley Youngs

Journal of the American Chemical Society, 1990

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Diastereoselective Aldol Reactions of Enolates Generated from Vicinally Substituted Trimethylsilylmethyl Cyclopropyl Ketones

Veejendra Yadav

Organic Letters, 2003

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β-Amino tertiary cycloalkanols for the enantioselective protonation of enolic species produced by a palladium-induced cascade reaction

Jacques Muzart

Tetrahedron: Asymmetry, 1998

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Enantioselective Palladium-Catalyzed N-Allylation of Lactams

Mesut Fidan

ChemistrySelect, 2018

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Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Allylic Alkylation Reactions of Ketones

Douglas Behenna

Angewandte Chemie International Edition, 2009

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A Desilylative Approach to Alkyl Substituted C(1)‐Ammonium Enolates: Application in Enantioselective [2+2] Cycloadditions

David Cordes

Angewandte Chemie

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Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies

Douglas Behenna

Chemistry - A European Journal, 2011

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Acyl palladium species in synthesis: single-step synthesis of ?,?-unsaturated ketones from acid chlorides

Russell Cox

Organic & Biomolecular Chemistry, 2007

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Catalytic Enantioselective Allylations of Acetylenic Aldehydes via 2-Propanol-Mediated Reductive Coupling

Alexander Burns

Organic Letters

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Enantioselective γ-Lactam Synthesis via Palladium-Catalyzed Intramolecular Asymmetric Allylic Alkylation

Peter Fristrup

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Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

Jimin Kim

Nature Chemistry, 2011

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Diastereoselective aldol reactions using .beta.-keto imide derived enolates. A versatile approach to the assemblage of polypropionate systems

George Sheppard

Journal of the American Chemical Society, 1990

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B(C 6 F 5 ) 3 -Catalyzed Allylation of Propargyl Acetates with Allylsilanes

Michael Rubin

Organic Letters, 2004

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Base mediated regioselective synthesis of highly functionalized conjugated enones

Surjeet Singh

Tetrahedron Letters, 2015

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Vinylation of cyclohexanone enolates using vinyl ether-iron complexes. Diastereoselectivity of carbon-carbon bond formation

Tony Chang

Organometallics, 1987

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Highly Stereoselective Kinetic Enolate Formation: Steric vs Electronic Effects

Linfeng Xie

The Journal of Organic Chemistry, 1997

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ChemInform Abstract: Regio- and Stereoselectivity in the Cyclization of Enolates Derived from 4,5-, 5,6-, and 6,7-Epoxy-1-phenyl-1-alkanones. Competition Between C- and O-Alkylation

Valeria Di Bussolo

Cheminform, 2010

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