Materials for solid-state gas sensors (original) (raw)
Abstract
The major problems in the development of inorganic gas-sensor materials are discussed. The general principle of semiconductor gas sensors is considered, and the band-structure parameters sensitive to the gas-phase composition are determined. Ways of improving sensor selectivity are examined. The composition, microstructure, and gas sensitivity of nanocrystalline SnO 2 and ZnO are investigated. The dopant content and grain size of Ni-doped SnO 2 are optimized for H2S detection. The prospects of employing systems of two or more nanocrystalline oxides (nanocomposites) for gas detection are discussed.
Loading Preview
Sorry, preview is currently unavailable. You can download the paper by clicking the button above.
References (25)
- Gopel, W., Ultimate Limits in the Miniaturization of Chemical Sensors, Sens. Actuators, A, 1996, vol. 56, pp. 83-102.
- Moseley, P.T., Materials Selection for Semiconductor Gas Sensors, Sens. Actuators, B, 1992, vol. 6, pp. 149-156.
- Khairutdinov, R.E, Chemistry of Semiconductor Nano- particles, Usp. Khim., 1998, vol. 67, pp. 125-139.
- Shull, R.D., Viewpoint: Nanocrystalline and Nanophase Materials, J. Nanostruct. Mater., 1993, vol. 2, pp. 213-216.
- Myasoedov, B.F. and Davydov, A.V., Chemical Sensors: Potentialities and Prospects, Zh. Anal. Khim., 1990, vol. 45, no. 7, pp. 1259-1278.
- Bechstedt, T. and Enderlein, R., Semic~176 Surfaces and Interfaces: Their Atomic and Electronic Structures, Berlin: Akademie, 1988. Translated under the title Poverkhnosti i granitsy razdela poluprovodnikov, Mos- cow: Mir, 1990.
- Henrich, V.E. and Cox, P.A., The Surface Science of Metal Oxides, Cambridge: Cambridge Univ. Press, 1993.
- Mizsei, J., How Can Sensitive and Selective Semicon- ductor Gas Sensor Be Made?, Sens. Actuators, B, 1995, vol. 23, pp. 173-176.
- Williams, D.E., Conduction and Gas Response of Semi- conductor Gas Sensors, Solid State Gas Sensors, Mosely, P.T. and Tofield, B.C., Eds., Philadelphia: Alam Higer, 1987.
- Souteyrand, E., Transduction Electrique pour la dEtec- tion de gaz dans les capteurs chimiques, Lyon: CMC2, 1997.
- Lalauze, R., Pijolat, C., Vincent, S., and Bruno, L., High Sensitivity Materials for Gas Detection, Sens. Actuators, B, 1992, vol. 8, pp. 237-243.
- Norris, J., The Role of Precious Metal Catalysts, Solid State Gas Sensors, Mosely, P.T. and Tofield, B.C., Eds., Philadelphia: Alam Higer, 1987, pp. 124-138.
- Tofield, B.C., Tin Dioxide Gas Sensors: Part 2. The Role of Surface Additives, J. Chem. Soc., Faraday Trans. 1, 1988, vol. 84, no. 2, pp. 441--457.
- Boccuzzi, E and Guiglielminotti, E., IR Study of TiO 2- Based Gas-Sensor Materials: Effect of Ruthenium on the Oxidation of NH 3, (CH3)3N, and NO, Sens. Actuators, B, 1994, vol. 21, pp. 27-31.
- Lim, C. and Oh, S., Microstructure Evolution and Gas Sensitivities of Pd-Doped SnO2-Based Sensor Prepared by Three Different Catalyst-Addition Processes, Sens. Actuators, B, 1996, vol. 30, pp. 223-231.
- Labeau, M., Gautheron, B., Cellier, E, et al., Pt Nano- particles Dispersed on SnO 2 Thin Films: A Microstruc- tural Study, J. Solid State Chem., 1993, vol. 102, pp. 434-439.
- Gaidi, M., Labeau, M., Chenevier, B., and Hazemann, J.L., In-situ EXAFS Analysis of the Local Environment of Pt Particles Incorporated in Thin Films of SnO 2 Semicon- ductor Oxide Used as Gas Sensors, Sens. Actuators, B, 1998, vol. 48, pp. 277-284.
- Xu, Ch.N., Tamaki, J., Miura, N., and Yamazoe, N., Nature of Sensitivity Promotion in Pd-Loaded SnO 2 Gas Sensor, J. Electrochem. Soc., 1996, vol. 143, no. 7, pp. LI48-L150.
- Shannon, R.D. and Prewitt, C.T., Effective Ionic Radii in Oxides and Fluorides, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem., 1969, vol. 25, no. 5, pp. 925-946.
- Danot, M., Afanasov, M.I., Ryabchikov, A.A., et al., Local Environment and Dynamic Characteristics of the ll9Sn(II) and 119Sn(IV) Mtssbauer Probes on the Sur- face of Cr203 Exposed to H2S Atmosphere, Solid State Commun., 1996, vol. 99, no. 4, pp. 249-254.
- Ghiotti, G., Chiorino, A., Pan, W.X., and Marchese, L., A Comparative Study of SnO 2 and CrO3/SnO 2 Powders: Their Microstructure and Their Different Response to CO, NO, H 2, and CH 4 Atmospheres, Sens. Actuators, B, 1992, vol. 7, pp. 691--699.
- Ghiotti, G., Chiorino, A., and Pan, W.X., Surface Chem- istry and Electronic Effects of H 2 (D2) on Pure SnO2 and Cr-Doped SnO 2, Sens. Actuators, B, 1993, vol. 15/16, pp. 367-371.
- Boulova, M.N., Pagnier, T., Rumyantseva, M.N., et al., In situ Study of the Reactivity of SnO2 Nanocrystallites with H2S by Coupled Electrical and Raman Measure- ments, NATO Sci. Ser., Ser. 3: High Technol., 1998, vol. 62, pp. 285-290.
- Tamaki, J., Maekawa, T., Miura, N., and Yamazoe, N., CuO-SnO2 Element of Highly Sensitive and Selective Detection of H2S, Sens. Actuators, B, 1992, vol. 9, pp. 197-203.
- Rumyantseva, M.N., Vasiliev, R.B., Kutsenok, I.B., et al., Thermodynamic Approach to the Development of H2S Selective SnO 2 Based Gas Sensors, Proc. llth Europ. Conf. on Solid-State Transducers, Eurosensors XI, Warsaw, 1997, vol. 1, pp. 503-506.