Recovery improvement of coarse particles by stage addition of reagents in industrial copper flotation circuit (original) (raw)
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Energy Sources, Part A: Recovery, Utilization, and Environmental Effects, 2018
Obtaining high recovery in copper flotation plants has been always under investigation in recent years. Misreported copper into tailing dramatically declines copper recovery. This study aims to find the possible reasons of copper loss to tailing and present the methods to improve the performance of the Sarcheshmeh copper plant flotation circuit. This work was performed in two phases. In the first stage, two surveys were carried out in an industrial plant for evaluation of floatability of two different types of copper ore (sulfide and mixed copper ores comprising sulfide and oxide minerals) and investigation of misreported copper into tailing. In the second stage, influence of particle size distribution in different levels, the collector (Z11 + R407), and sulfidisation agent (NaHS) dosages were investigated on the floatability of mixed copper ore, and possible improvement of copper recovery ores was evaluated by a series of batch flotation experiments. Almost 95% of overall copper loss in final tailing took place in the rougher circuit. The overall recovery of mixed copper ores was obtained 8% less than the other survey. It was found that an important factor of recovery reduction was due to increasing oxide copper proportion in rougher feed. Results of size-by-size recovery analysis showed that the highest sulfide copper loss occurred in coarse particles (>74 µm) and the highest oxide copper loss happened in fine particles (<9 µm). From batch flotation experiments, it was found that the ultimate recovery increased to a certain value with increasing the collector dosage (50 g/t) and thereafter reduced. Increasing the NaHS dosage to 800 g/t resulted in 4.5% increase in recovery from 79.3% to 83.8% with a significant increase in grade. It is observed that size reduction of coarse particles (>74 μm) of rougher tailing and then their flotation have significant effect on increasing overall recovery from 79.3% to 82.2%. Experimental studies showed that the use of the proposed methods with considering the optimized conditions in the plant can be led to an increase in copper recovery from 79% to 87% without any decrease in grade.
The effect of mixed collectors in the rougher flotation of sungun copper
2013
The use of mixtures of collectors has long been recognised in plant practice and has been shown to enhance flotation performance. These benefits have been reported for a wide range of collector mixtures (anionic, cationic and non-ionic) and include lower dosage requirements, improved selectivity and rates and extents of recovery and an increase in the recovery of coarse particles. Thus, knowing about these interactions can help to improve the present situation greatly. The goal of the present research is to study the effect of the composition of the collector on copper and iron recovery from porphyry ore. In this research the performance of collectors has been investigated in Pure and in the mixture form. To do so, we have used the collectors of Xanthates, dithiophosphates and thionocarbamates. The results of combination of the collectors showed that the best Cu recovery has been achieved with %92.20 in the compositions of the collectors of SIPX with SIBDTM (a mixture of mercapto be...
Flotation Characteristics of a Complex Copper Ore: a Comparison Between Wet and Dry Grinding
It is known that the grinding condition has a major effect on the beneficiation characteristics of the minerals in subsequent processing, in particular, flotation. In the flotation process, particles surface and their condition can significantly influence collector adsorption and flotation performance. For example, particle shape and its surface roughness occurred during grinding may influence flotation characteristics of a specific ore. In fact, adsorption of different cationic and anionic species on mineral surfaces can be varied depending on the selected comminution procedure. The flotation performance of sulphide minerals can be detrimentally affected by the surface oxidation. The amount of surface oxidation may reduce the hydrophobicity of the mineral and makes adsorption of collectors less selective. Improved liberation may generally result in improved flotation recovery. However, this may result in finer grinding and slimes, and consequently, reduce the overall flotation recovery. This paper discusses the effect of wet and dry grinding on copper flotation of a complex Cu-Pb-Zn ore. Industrially, wet grinding is preferred due to its higher energy efficiency and owing to downstream processing requirements. In this study, series of flotation tests were conducted,and surface analysis (XPS and ToFSIMS) were performed after wet or dry grinding at two different P 80 values. Mineralogical study was also conducted to investigate the liberation of valuable minerals after grinding. A higher copper flotation recovery was found for wet grinding. However, the copper recovery was increased by further grinding in both conditions (wet and dry). The results showed a higher collector adsorption on copper mineral surfaces after wet grinding. The surface analysis also revealed that the ore is slightly more oxidized after dry grinding probably due to higher temperature during dry grinding.
EJERS, 2021
Copper and cobalt demand is projected to be increased from here to 2050 and the challenge is to find treat economically minerals which contains those metals. Several tailings from oxide ores throughout the word contain good grades of copper and cobalt that should be recovered by froth flotation. This paper investigates the recovery of copper and cobalt through reprocessing of spiral classifier tailings by determination of specific reagents dosage. The flotation behaviours of malachite and heterogenite were studied through many roughing and cleaning flotation tests in order to recovery most of copper and cobalt. The effect of specific reagents was be varied and others parameters were kept constant. The highest recoveries of both copper and cobalt in rougher concentrate were respectively 82.51% and 72.51% with grades of 12.52% and 0.99% respectively. However, the cleaner concentrate was 24.54 Cu% and 1.38% Co with recoveries of 69.26 % and 40.7% respectively. It was concluded that the reprocessing of spiral classifier tailings through froth flotation is benefit because it recovers most of desired metal and reduces the risk of their presence on environment through plant tailings. Recycling of cleaner tailings was also proposed.
Copper Upgrading and Recovery Process from Mine Tailing of Bor Region, Serbia Using Flotation
International Journal of the Society of Materials Engineering for Resources, 2014
A process for concentration of Cu from a Cu mine tailing by flotation has been investigated in this study. The flotation studies were carried out under varying conditions of pH (3.5~12), flotation time (0~20 minutes) and sulfurizing reagent (0, 1000 g/t) using two different pH regulators (NaOH, Ca(OH) 2). The results showed that the grade of Cu in froth concentrate was increased from 0.24 mass% to 0.81 mass% with the enrichment ratio of 4, whereas the Cu recovery reached 60% under the conditions (pH 10, sulfurizing reagent: 1000 g/t, collector of PAX: 100 g/t, frother of MIBC: 200 g/t and flotation time: 5 minutes). At the condition, the grade of Al and Fe were reached to 0.6 mass% and 6.6 mass% from 3.45 mass% and 3.51 mass%, respectively.
Mining and Metallurgy Engineering Bor, 2014
One of the influential parameters on the process of flotation concentration is a coarseness of particles and openness of mineral resources. In the process of flotation concentration of ore from the deposit Veliki Krivelj, the grinding fineness since the opening of the mine in 1982 has been maintained at values around 58% -0.074 mm. Since then, the operation descended into the deeper parts of deposit, the copper content decreased in the ore and it was assumed that the optimal fineness of ore grinding was changed. This paper presents the results of testing the fineness of grin-ding on recovery and copper content of the basic copper concentrate and the impact of regrinding on recovery and copper content in the purified copper concentrate on a sample of ore from the deposits Veliki Krivelj. The laboratory experiments flotation concentration were carried out, the balances of concentration were made and it is concluded that finer grinding is necessary for better concentration. The optimal...
A New Collector for Effectively Increasing Recovery in Copper Oxide Ore-Staged Flotation
Minerals, 2019
A new method, staged flotation for effectively increasing the recovery of ultra-fine copper oxide ore with a new type of collector (ZH-1, C3-5 carbon chain xanthate) is proposed for the first time. The flotation process and mechanism were examined by flotation tests, entrainment rate analysis, laser particle size experiments and microscopic imagery as well as economic feasibility analysis. It was demonstrated that the collector isoamyl sodium xanthate (ISX) shows a good collection ability (recovery exceeded 95%) for azurite, but the recovery was relatively much lower for malachite (only near 80%) due to the different particle size distribution. The new type of xanthate ZH-1 has shown a high-efficiency collection performance for fine-grained malachite. The recovery achieved for −10 μm malachite was more than 95% when the ZH-1 dosage was 150 mg/L, while the average particle size of −10 μm malachite sharply increased from 4.641 μm to 9.631 μm. The batch flotation results indicated that...
Optimization of reagent dosages for copper flotation using statistical technique
Transactions of Nonferrous Metals Society of China, 2010
The effects of Z11 and AP407 collectors as well as AF65 and AF70 frothers were evaluated in the rougher flotation circuit of the Sungun copper concentrator plant using 2 4 full factorial design. Response functions were produced for both Cu grade and recovery and optimized within the experimental range. The optimum reagent dosages were found to be 12.01 g/t Z11, 11 g/t AP407, 3 g/t AF65 and 5 g/t AF70 to attain the maximum Cu grade (8.17%). The reagent dosages of 12 g/t Z11, 11 g/t AP407, 3 g/t AF65 and 15 g/t AF70 produced the maximum Cu recovery (86.44%). The collector distribution demonstrated that the distribution pattern of (32%, 32%, 20%, 16%) can produce the best recovery (87.75%) in comparison to other examined distribution patterns.
Modified column flotation of mineral particles
International Journal of Mineral Processing, 1996
This work summarizes flotation results obtained in a modified column which selectively separates drained particles from the froth zone and uses a secondary wash water system between the feed and the froth zone. Flotation results on gold, copper, lead-zinc and fluorite ores are reported. The combination of separating the froth drop-back material as a "third-product" and secondary washing improved, the concentrate grades when compared to the conventional column cell. When the modified column was used for "rougher flash" flotation or as a cleaner of copper ores; clean copper concentrates analyzing 33-40% copper were obtained (33% recovery). Flotation recovery of gold from tailings was as much as 15%, with concentrate grades higher than 160 g/t. As a cleaning stage in lead-zinc ore flotation, recoveries of both sulfides were of the order of 92-94% with grades up to 80-82%, as compared to 70% in the "conventional" column. With the fluorite ore, recoveries of the order of 94%, were achieved with high selectivity (about 96% CaF,) at high flotation rates. The performance of the modified column is better than the conventional column due to improved mass transfer conditions. Finally, data on the influence of some cell design parameters are reported and the potential practical applications of this type of cell are discussed.
Parametric Optimization in Rougher Flotation Performance of a Sulfidized Mixed Copper Ore
Minerals, 2020
The dominant challenge of current copper beneficiation plants is the low recoverability of oxide copper-bearing minerals associated with sulfide type ones. Furthermore, applying commonly used conventional methodologies does not allow the interactional effects of critical parameters in the flotation processes to be investigated, which is mostly overlooked in the literature. To tackle this issue, the present paper aimed at characterizing the behavior of five key effective factors and their interactions in a sulfidized copper ore. In this context, dosage of collector (sodium di-ethydithiophosphate, 60-100 g/t), depressant (sodium silicate, 80-120 g/t) and frother (methyl isobutyl carbinol (MIBC), 6-10 g/t), pulp pH (7-11) and agitation rate (900-1300 rpm) were examined and statistically analyzed using response surface methodology. Flotation experiments were conducted in a Denver type agitated flotation cell at the rougher stage. The experimental results showed that increasing the pH (from 8 to 10) at low agitation rate (1000 rpm) enhanced the recovery from 80.36% to 85.22%, while at high agitation rate (1200 rpm), a slight declination occurred in the recovery. Meanwhile, increasing the collector dosage at a lower frother value (7 g/t), caused a reduction of about 4.44% in copper recovery owing to the interactions between factors, whereas at a higher frother level (9 g/t), the recovery was almost unchanged. The optimization process was also performed using the goal function approach, and maximum copper recovery of 92.75% was obtained using~70 g/t collector, 110 g/t depressant, 7 g/t frother, pulp pH of 10 and 1000 rpm agitation rate.