Magnetic properties of hot pressed powder Co68Fe4Mo1Si13.5B13.5 alloy (original) (raw)

Purpose: The aim of the work is to investigate the structure and magnetic properties of the cobalt based hot pressed Co68Fe4Mo1Si13.5B13.5 powder obtained in high-energy ball milling process. Design/methodology/approach: The nanocrystalline ferromagnetic powders were manufactured by high-energy ball milling of metallic glasses ribbons in as state. The hot pressing process was made on machine “Degussa”. Observations of the structure of die stampings were made on the OPTON DSM-940 scanning electron microscope. Graphical analyses of the obtained X-ray diffraction patterns, as well as of the HC=f(TA) relationship were made using the MICROCAL ORIGIN 6.0 program. Findings: The analysis of the magnetic properties and structure of the die stamping out that compared to the magnetic properties of the amorphous ribbons as their precursor, that hot pressing process deteriorates their magnetically soft properties. Research limitations/implications: For the metallic Co-based amorphous ribbons, further mechanical and structure examinations are planed. Practical implications: Structure and magnetic properties analysis of die stampings of powdered amorphous metallic ribbons is helpful to prepare this material by laboratory methods. Feature an alternative to commercial alloys and composite materials are the amorphous and nanocrystalline metal amorphous ribbons obtained by melt spinning technique and make it possible to obtain the new composite materials with best magnetic properties, which dimensions and shape can be freely formed Originality/value: The paper presents influence of hot pressing parameters process of metallic powdered ribbons on structure and magnetic properties of obtained die stampings.

Structure and magnetic properties of hot pressed powder Co77Si11.5B11.5 alloy

Journal of Achievements in Materials and Manufacturing Engineering, 2008

Purpose: The aim of the work is to investigate the structure and magnetic properties of the cobalt based hot pressed Co77Si11.5B11.5 powder obtained in high-energy ball milling process. Design/methodology/approach: The nanocrystalline ferromagnetic powders were manufactured by highenergy ball milling (SPEX 8000 mill) of metallic glasses ribbons in as state. The hot pressing process was made on machine “Degussa”. Observations of the structure of die stampings were made on the OPTON DSM-940 and ZEISS SUPRA 35 scanning electron microscope. Tests of magnetic properties were carried out by the use of Lake Shore’s Vibrating Sample Magnetometer VSM model 7307. Findings: The analysis of the results enabled determination of the hot pressing parameters on magnetic properties and structure of obtained stampings. Research limitations/implications: For the metallic Co-based amorphous ribbons, further mechanical and structure examinations are planed. Practical implications: Structure and magnetic properties analysis of die stampings of powdered amorphous metallic ribbons is helpful to prepare this material by laboratory methods. Feature an alternative to commercial alloys and composite materials are the amorphous and nanocrystalline metal amorphous ribbons obtained by melt spinning technique and make it possible to obtain the new composite materials with best magnetic properties, which dimensions and shape can be freely formed. Originality/value: The paper presents influence of hot pressing parameters process of metallic powdered ribbons Co77Si11.5B11.5 on structure and magnetic properties of obtained die stampings.

Influence of temperature on structure and magnetic properties of powders alloys

2007

Purpose: The paper presents the research results of nanocrystalline powders obtained by high energetic milling of amorphous ribbons based on cobalt Co77Si11,5B11,5 and Co68Fe4Mo1Si13,5B13,5. Design/methodology/approach: A 8000 SPEX CertiPrep Mixer/Mill high energy ball mill was applied to mill the ribbons both in „as quenched” state and heat treated. Observations of the structure of powders were made on the Opton DSM-940 scanning electron microscope. The change of powder material structure was measured with electron transmitting microscope JEOL JEM 200CX and X-ray analysis. The X-ray tests were realized with the use of the XRD 7 SEIFERT-FPM diffractometer. Findings: The analysis of the magnetic properties test results of the of the Co77Si11.5B11.5 and Co68Fe4Mo1Si13,5B13,5 powders obtained in the high-energy ball of milling process proved that the process causes significant decrease in the magnetic properties. The structure and magnetic properties of this material may be improved by means of a proper choice of parameters of this process as well as the final thermal treatment. Research limitations/implications: For the powders, further magnetical, structure and composition examinations are planed. Practical implications: The amorphous and nanocrystalline powders of Co77Si11,5B11,5 and Co68Fe4Mo1Si13,5B13,5 alloys obtained by high-energy ball milling of metallic glasses feature an alternative to solid alloys and make it possible to obtain the ferromagnetic nanocomposites, whose shape and dimensions can be freely formed. Originality/value: The paper presents influence of annealing temperature and parameters of the high-energy ball milling process on structure and magnetic properties of soft magnetic powder materials obtained in this technique. Results and a discussion of the influence of high energy mechanical milling process on particle size and their distribution and annealing temperature of powders as well as structure and magnetic properties of investigated samples is presented. According to achieved results it has been attempted to describe the possibilities of improvement the soft magnetic properties of obtained powder materials

Structure and magnetic properties of powder soft magnetic materials

2007

AbstrAct Purpose: The paper presents influence of high-energy mechanical milling process, isothermal annealing and to a combination of these two technologies of cobalt base metallic glasses Co 77 Si 11.5 B 11.5 on magnetic properties and their structure. Design/methodology/approach: The powder test piece obtained from the input amorphous ribbon in highenergy ball milling. The diffraction examinations and examinations of thin foils were made on the JEOL JEM 200CX transmission electron microscope. Observations of the structure of powders were made on the Opton DSM-940 scanning electron microscope. The X-ray tests were realized with the use of the XRD 7 SEIFERT-FPM diffractometer. Findings: analysis of the magnetic properties test results of the of the Co 77 Si 11.5 B 11.5 powders obtained in the high-energy ball of milling process proved that the process causes significant decrease in the magnetic properties. The structure and magnetic properties of this material may be improved by means of a proper choice of parameters of this process as well as the final thermal treatment. Research limitations/implications: For the powders, further magnetical, structure and composition examinations are planed. Practical implications: The amorphous and nanocrystalline metal powders obtained by high-energy ball milling of metallic glasses feature an alternative to solid alloys and make it possible to obtain the ferromagnetic nanocomposites, whose shape and dimensions can be freely formed. Originality/value: The paper presents influence of parameters of the high-energy ball milling process on structure and magnetic properties of soft magnetic powder materials obtained in this technique. Results and a discussion of the influence of high energy mechanical milling process on particle size and their distribution as well as structure and magnetic properties of investigated samples is presented.

Structure and properties of the powder obtained from the amorphous ribbon

AbstrAct Purpose: The aim of the work is to investigate the magnetic properties of the cobalt based Co 68 Fe 4 Mo 1 Si 13.5 B 13.5 amorphous alloy subjected to the isothermal annealing, high-energy milling and to a combination of these two technologies. Design/methodology/approach: The powder test piece obtained from the input amorphous ribbon in highenergy ball milling. Distributions of the magnetic hyperfine P(H) fields were determined for spectra smoothed in this way, by using the HFQS program, employing the Hesse-Rübartsch method. The diffraction examinations and examinations of thin foils were made on the JEOL JEM 200CX transmission electron microscope. Observations of the structure of powders were made on the Opton DSM-940 scanning electron microscope. Findings: The analysis of the magnetic properties test results of the of the Co 68 Fe 4 Mo 1 Si 13.5 B 13.5 powders obtained in the high-energy ball of milling process proved that the process causes significant decrease in the magnetic properties. The structure and magnetic properties of this material may be improved by means of a proper choice of parameters of this process as well as the final thermal treatment. Research limitations/implications: For the powders, further magnetical, structure and composition examinations are planed. Practical implications: The amorphous and nanocrystalline metal powders obtained by milling of metallic glasses feature an alternative to solid alloys and make it possible to obtain the ferromagnetic nanocomposites, whose shape and dimensions can be freely formed. Originality/value: The paper presents influence of parameters of the high-energy ball milling process on structure and magnetic properties of soft magnetic powder materials obtained in this technique. The paper compares structure and magnetic properties of the Co 68 Fe 4 Mo 1 Si 13.5 B 13.5 alloy obtained in high-energy ball milling process and melt spinning technique.

Magnetic and microstructural properties of the mechanically alloyed Fe57Co21Nb7B15 powder mixture

Materials Chemistry and Physics, 2012

Partially amorphous Fe 57 Co 21 Nb 7 B 15 powder mixture was prepared by mechanical alloying in a high energy planetary ball-mill under argon atmosphere. Thermal stability, magnetic properties, structural and morphological changes during the milling process were followed by differential scanning calorimetry, vibrating sample magnetometry, X-ray diffraction and scanning electron microscopy. A duplex nanostructure of Fe(Co) and Fe-boride nanocrystals within an amorphous matrix is achieved on further milling time. Depending on the structural state of the milled powders, two or several overlapping exothermic peaks over the temperature range 100-700 • C were revealed in the DSC scans. The saturation magnetization and coercivity values are of about 111 emu g −1 and 59 Oe, respectively, after 96 h of milling.

Magnetic properties of Co-based amorphous ribbon under cyclic heating and cooling

ISSUES, 2010

Purpose: The aim of the work is to investigate the changes of magnetic properties of the cobalt based Co68Fe4Mo1Si13.5B13.5 alloy under cycling heating and cooling. Design/methodology/approach: The amorphous metallic ribbons were manufactured by planar-flow-casting method. Investigations of the magnetic properties were observed under permanent heating amorphous and partially crystallized alloy. Observations of the structure were made on the JOEL transmission electron microscope (TEM). Using the HFQS program the distributions of the magnetic hyperfine P(H) fields were determined for spectra smoothed in this way, employing the Hesse-Rübartsch method. Findings: The analysis of the magnetic properties under permanent heating and structure of the Co-based amorphous ribbons obtained in the by planar-flow-casting process proved that the permanent heating caused the crystallization of second magnetic phase after transition near to paramagnetic state. Research limitations/implications: The appropriate cyclic heating and cooling significantly decreasing soft magnetic properties of examined amorphous alloy. The cyclic heating beginning of elementary crystallization processes and the end of crystallization alloy. Practical implications: According to the results presented in the paper the examined Co-based glassy alloys as a soft ferromagnetic material may be utilized in construction of magnetic cores such as choke coils, common mode and noise filter and is of great technological interest. Originality/value: The paper presents influence of permanent heating on structural changes of metallic ribbons. Results and discussion of the influence of permanent heating on magnetic properties of metallic ribbon are presented.

Magnetic properties of high-energy milled Fe78Si13B9 nanocrystalline powders and powder-based nanocomposites

Journal of Materials Processing Technology, 2004

The paper deals with the combined influence of the thermal nanocrystallization temperature and time and the milling time on the properties of the nanocrystallization process and the structure of powders based on METGLAS (metallic glass). Thermal treatment of Fe78Si13B9 metallic glass was carried out for 1 h at the temperature range of 100–600 °C with 50 °C temperature steps. The heat treated material was then processed by high-energy milling. It was shown, that the use of a combination of thermal nanocrystallization and high-energy milling produced metallic glass-based nanocrystalline powders containing Fe-α, Fe3B and Fe2B crystallites in the amorphous matrix. Then, the nanocrystalline powders were used to construct composite toroidal cores.

Structure and magnetic properties of powder HITPERM material

The aim of the work is to investigate the structure and magnetic properties of the cobalt based HITPERM amorphous alloy Co 68 Fe 4 Mo 1 Si 13.5 B 13.5 subjected high-energy ball milling and to the isothermal annealing to a combination of these two technologies.

Influence of production method on the magnetic parameters and structure of Fe61Co10Y8Nb1B20 amorphous alloys in the as-quenched state

Journal of Alloys and Compounds, 2014

In this paper, the influence of production method on the basic magnetic properties and structure of amorphous alloys, in the forms of ribbons and plates, was investigated. The samples used in the investigations were obtained by three different production methods: ultrafast cooling of the liquid alloy on a rotating copper wheel (the melt-spinning method), and the injection or suction of the molten alloy into a water-cooled copper die injection-and suction-casting, respectively. The structure of the resulting samples of Fe 61 Co 10 Y 8 Nb 1 B 20 alloy was investigated by means of X-ray diffractometry, Mössbauer spectroscopy and scanning electron microscopy. The results of the microstructural investigations confirmed that the obtained samples were amorphous and without crystalline precipitations. The images from the scanning electron microscope were typical for amorphous materials. Magnetic measurements were performed using a vibrating sample magnetometer (VSM) using magnetic fields of up to 2 T. The highest value of the saturation magnetization was achieved for the sample which was in the form of a ribbon. The values of this parameter for the samples which were in the form of plates were similar to each other, regardless of the production method. The values of the coercivity showed much greater differences, depending on the production method. The smallest value of coercivity was found for the sample in plate-form obtained by injection-casting; this is connected with the highest value of structural relaxation in the investigated material.

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