Organometallic models for the hydrodesulphurisation (HDS) reaction: synthesis of [(η-thiophene)M(PPh3)2]+ (M = Rh, Ir) and x-ray structure of the Rh derivative, the first example of a fully characterised π-thiophene complex of an HDS-active metal (original) (raw)

Journal of Organometallic Chemistry, 1986

Jose Puga

Antonio Tiripicchio

Abstract

Abstract Hydrogenation of [(NBD) M (PPh 3) 2][PF 6](M= Rh, Ir; NBD= norbornadiene) in CH 2 Cl 2/thiophene gives [(η-thiophene M (PPh 3) 2]+(M= Rh, Ir) compounds, which have been isolated and characterised. In the case of [(η-thiophene) Rh (PPh 3) 2]+ the structure has ...

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