PORTUGALIAE ELECTROCHIMICA ACTA Review on Mechanistic Action of Inhibitors on Steel Corrosion in Acidic Media (original) (raw)
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Development of new corrosion inhibitor tested on mild steel supported by electrochemical study
Results in Physics, 2018
Mild steel is a metal which is commonly used in industrials and manufacturing of equipment for most industries round the world. It is cheaper cost compared with the other metals and its durable, hard and easy-to-wear physical properties make it a major choice in the manufacture of equipment parts. The main problem through the uses of mild steel in industry is its resistance against corrosion, especially in acidic solutions. This case led to raise the cost of maintenance of equipment that used mild steel and as a result increased costs for the company. Organic corrosive inhibitors that also act as green chemicals, 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazolhave been synthesized. This inhibitor is tested as corrosion inhibitor on a mild steel sample MS in 1M hydrochloric acid solution (HCl) using electrochemical measurements test includes PD (Potentiodynamic), EIS (Electrochemical impedance spectroscopy), OCP (Open circuit potential) and EFM (electrochemical frequency modulation). The obtained results indicate that 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazol acts as a good corrosion inhibitor for mild steel sample in HCl solution with efficiency above 90%. Changes in the impedance parameters postulated adsorption on the mild steel specimens' surfaces of, which it going to the formation of protective coating layer. It also shows that 4-hydroxybenzylideneaminomethyl-5-ethyl-1,3,4-thiadiazolcorrosion inhibitors are 2 effective in helping to reduce and slow down the corrosion process that occurs on mild steel surface in hydrochloric acid solution. Increase of corrosion inhibitor concentration provides a protective layer of mild steel. However, this protective layer becomes weak when the temperature of the solution increases.
Mitigation of Mild Steel Corrosion in Acidic Solution Using Inhibitor
E-Journal of Chemistry
The inhibition efficiency of mild steel corrosion in HCl acidic solution containing various concentrations of mixed inhibitors were evaluated by conducting Tafel polarization and electrochemical impedance studies. The mixed inhibitors used in this present investigation were trisodium citrate and sodium benzoate. In this present investigation 0.01 N to 0.1 N concentrations of HCl was used at 30°C. Sodium benzoate present in the mixed inhibitive system enhanced the inhibition efficiency through chemisorptions. The maximum inhibition efficiency ( 95.4%) was obtained for the mixed inhibitive system containing 0.05 M citrate and 0.5 M benzoate in 0.1 N HCl.
The corrosion inhibition of mild steel in one normal sulphuric acid solution by PEGME has been studied in relation to the concentration of the inhibitor as well as the temperature using electrochemical polarization (galvanostatic and potentiostatic) techniques. The results were supplemented with scanning electron microscopy and infra-red spectroscopy. All the methods employed are in reasonable agreement. There is no particular relationship of inhibition with concentration and temperatures. The thermodynamic functions of dissolution and adsorption processes were calculated from experimental polarization data and the interpretation of the results is given. Adsorption of PEGME was found to follow the Langmuir's adsorption isotherm. PEGME is a mixed type of inhibitor.
The corrosion inhibition of mild steel in one normal sulphuric acid solution by brij-30 has been studied in relation to the concentration of the inhibitor as well as the temperature using electrochemical polarization (galvanostatic and potentiostatic) techniques. The results were supplemented with scanning electron microscopy and infra-red spectroscopy. All the methods employed are in reasonable agreement. There is no particular relationship of inhibition with concentration and temperatures. The thermodynamic functions of dissolution and adsorption processes were calculated from experimental polarization data and the interpretation of the results is given. Adsorption of Brij-30 was found to follow the Langmuir's adsorption isotherm. Brij-30 is a mixed type of inhibitor.
Inhibition of Acid Corrosion of Mild Steel
The inhibition efficacy of aqueous extracts of the leaves of Delonixregia (DR) in 1 M HCl and 0.5 M H 2 SO 4 have been investigated using weight loss, electrochemical and surface probe techniques. DR extract inhibited mild steel corrosion in both acidic environments via adsorptionof the extract organic matter on the metal/solution interface.Potentiodynamic polarization results indicate that DR is a mixed type inhibitor in both acidic environments, whereas the impedance results revealed adsorption of the DR species on a corroding steel surface. Increase in inhibition efficiency was concentration dependent. The adsorption followed Langmuir adsorption isotherm. Scanning electron microscopy (SEM) results revealed the formation of a protective layer adsorbed on a mild steel surface in the acid solutions.
Review: Eco-Friendly Corrosion Inhibitors on Mild Steel in Acidic Medium
IRJET, 2022
Eco friendly corrosion inhibitors were chosen for this review, and their corrosion inhibition tendency was examined. The inhibitory property of these inhibitors on mild steel (MS) in an acidic environment are being explored. It was determined the rate of corrosion by the applications of chemical and electrochemical systems. Corrosion inhibition rises with inhibition efficiency and decreases with temperature, according to these studies. In all of these papers, on mechanisms of adsorption and thermodynamics were explored. Scanning Electron Microscopic investigations were used to discuss surface morphology. Few academics have recently published theoretical studies such as quantum studies. In this paper, all of the works have been discussed.
International Journal for Research in Applied Science & Engineering Technology (IJRASET), 2022
Benzoic acid, salicylic acid, Anthranilic acid, 2-Nitro benzoic acid, 2-Chlorobenzoic acid compounds containing acidic group as a corrosion inhibitor for carbon steel was investigated. The study revealed that the various group such as (-COOH, OH, Cl and-NO 2) containing in organic compounds has an inhibitory action on the corrosion of carbon steel in the investigated medium. Corrosion rate of mild steel was studied using chemical weight loss method at room temperature. This research paper presents use of carboxylic group organic compounds as corrosion inhibitors for metals in 0.1N, 0.01N and 0.001N (HCl, HNO 3 and H 2 SO 4) acidic medium. A common mechanism for inhibiting corrosion involves formation of a coating, often a passivation layer, which prevents access of the corrosive substance to the metal. Organic corrosion inhibitors adsorb on the surface to form protective film, which displace water and protect it against deteriorating. Effective organic corrosion inhibitors contain nitrogen, oxygen, sulphur and phosphorus with lone electron pairs as well can contain structural moieties with π-electrons that interact with metal favouring the adsorption process. This review presents mechanisms and monitoring of corrosion, laboratory methods for corrosion study, relationship between structure and efficacy of corrosion inhibitions, theoretical approach to design new inhibitors and some aspects of corrosion.
Most of the industries require water for cooling purpose. The major problems in the industrial use of cooling water systems are corrosion of the metal equipment, contamination of the circulating water with microorganisms and scale formation. Inhibition of corrosion and scaling can be done by the application of inhibitors. It is noted that the effect of corrosion inhibitors is always caused by change in the state of surface being protected due to adsorption or formation of hardly soluble compounds with metal cations. Review including extensive listing of various types of organic inhibitors has been published. The molecules most often used as corrosion inhibitors are nitrogen, sulphur, oxygen and phosphorous containing compounds [1-6]. These compounds get adsorbed onto the surface of metal from the bulk of environment forming a film at the metal surface. The inhibition efficiency increases in the order O < N < S < P [7]. The corrosion inhibition of metals in acidic media by different types of organic compounds has been widely studied [8-13]. The inhibition action of organic molecules is primarly due to their adsorption on the surface of the metal through the presence of active centres.
3 Natural Sci IJANS Inhibition of Acidic Corrosion 1
The inhibitive effect of symmetrical 1,3,4-oxadiazoles on the corrosion of mild steel in 1M H 2 SO 4 was investigated by weight loss method, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy. The results showed that inhibition efficiency increases with increase in concentration of the inhibitors. The potentiodynamic polarization curves revealed that the oxadiazoles act as mixed type inhibitors. EIS measurements show an increase in charge transfer resistance with the inhibitor concentrations. The temperature effect on the corrosion behaviour of the steel in 1M H 2 SO 4 with and without the inhibitor was studied in the temperature range (303-333K). The thermodynamic parameter ∆G 0 and kinetic parameter E a have also been calculated. The inhibition efficiency has been synergistically enhanced by the addition of halide ions. The percentage of iron in the corrodent solution was determined by atomic absorption spectroscopy. The surface morphology of the mild steel specimens were evaluated using SEM images.