Dose Optimization for Aluminium and Iron Based Coagulants viz., Aluminium Sulphate, Ferric Chloride and Ferrous Sulphate for COD Removal from Landfill Leachate at its Natural pH (original) (raw)

Preliminary Tests of Cod Removal from Landfill Leachate Using Coagulation-Flocculation Processes

Architecture Civil Engineering Environment, 2009

A b s t r a c t The preliminary tests of effective COD removal by coagulation-flocculation processes from landfill leachate were carried out. The municipal landfill, from which leachate was collected has been exploited since 2004. The leachate characterized with comparatively low contents of organic matters expressed as COD (2000-2600 mg O 2/L), and pH value within the range of 7.4-7.6. The coagulation process was conducted using 3 coagulants: PIX 110-10, Al 2(SO 4)3 and FeCl 3. The applied coag ulant doses were within the range of 100-2500 mg/L. In the first part of research the most profitable parameters of coagu lation were chosen. It was noted that the ferric coagulants were determined to have bigger treatment efficiency than alu minium sulphate. The highest effectiveness of COD removal (56%) was obtained when FeCl 3 was used in dose of 2100 mg/L. The worse efficiency (only about 44%) was observed when Al 2(SO 4)3 was used in coagulation process in dose of 1550 mg/L. In the seco...

Treatment of Landfill Leachate through Coagulation Process

Landfill leachate can be defined as a liquid that passes through the municipal solid waste (MSW) landfill and has extracted dissolved and suspended matter from it. The generation of leachate is a major problem for MSW landfills and causes significant threat to surface water and groundwater. Special care is required for efficient treatment and disposal. In addition, landfill leachate is complex waste water with considerable variation in both quality and quantity. The composition and concentration of pollutants are influenced by the types of waste deposited, hydro geological factors and more significant by the age of the landfill site. In general, leachate is highly contaminated with organic contaminants measured as chemical oxygen demand (COD), biochemical oxygen demand (BOD) and also with high ammonium nitrogen concentration. The main focused of this research is to investigate the performance of chemical treatment by coagulation process and to compare the efficiency of coagulants on removal of COD and TSS with standard tools in leachate samples which was collected from Rajbondh landfill in Khulna. The collected leachate samples were tested in the laboratory through the standard methods to measure the relevant parameters. The characteristics of leachate were: pH=8.6; BOD5=142.1 mg/L; COD=5760 mg/L; Temperature=28.7ºC; Electric Conductivity=5.67µs/cm; TS=17000 mg/L; TDS=16600 mg/L; TSS=400 mg/L; Turbidity=336 NTU; Color=17800 pt-co; Alkalinity=1700 mg/L; Salinity=2800 mg/L; T.C.=740; F.C.=300. The coagulation of leachate was accomplished by a technique consisted of Poly-Aluminum Chloride (PAC), Aluminum Sulphate (Al 2 (SO 4) 3 .18H 2 O) as Alum and Ferrous Sulphate (FeSO 4) in various dosages and different pH values (2, 5, 7 and 9). Results showed that the efficiency for COD removal by PAC at pH=9 and 2500 mg/L of coagulant dose, by Alum at pH=9 and 2500 mg/L of coagulant dose, by Ferrous Sulphate at pH=7 and 2000 mg/L of coagulant dose. The COD removal efficiency for PAC, Alum and Ferrous Sulphate were 81.82, 75 and 85.71% respectively. Results also showed that efficiency for TSS removal by PAC that was obtained at pH=5 and 2500 mg/L concentration of coagulant dose, by alum at pH=7 and 2500 mg/L concentration of coagulant dose and by ferrous sulphate at pH=9 and 2000 mg/L of coagulant dose. The TSS removal efficiency for PAC, Alum and ferrous sulphate are 46.15, 60 and 72.73% respectively. In this study carried out the COD and TSS removal efficiency both were better for ferrous sulphate. To depict the performance of used chemical coagulations then compared to the standards leachate discharge which are available in the literature.

Treatment of Landfill Leachate using Coagulation

Commercial/ conventional coagulant was used for the removal of COD and turbidity from landfill leachate containing COD 2451 mg/L. Coagulation studies were performed with lime and alum by varying parameters such as pH and coagulant dose. The experimental study shows that coagulation with calcium hydroxide and alum can remove up to 69% and 54% COD from the leachate. The optimum process variables of this coagulation study were found for calcium hydroxide and alum as pH 8 and 6; and coagulant dosage 25 g/L and 15 g/L, respectively.

Removal of COD and Colour from Sanitary Landfill Leachate by using Coagulation – Fenton’s Process

Journal of Applied Sciences and Environmental Management, 2009

This study investigated two methods for the removal of COD and colour from sanitary landfill leachates. The first method involved the use of coagulation/flocculation process using FeCl 3 as a conventional coagulant and Ca(OH) 2 as base-precipitant. The second method involved integration of Fenton's reagent into the coagulation/flocculation process. Concentration of FeCl 3 that reduced chemical oxygen demand (COD), and color by 37 and 62% is 1000mg/l. Fenton-coagulation flocculation process reduced the COD and color of the leachates by 88 and 98% respectively. The optimum conditions for the effectiveness of Fenton's reagent, namely temperature, pH, H 2 O 2 and coagulant dose were studied. @JASEM JASEM

Cod Removal from Landfill Leachate Using Fenton Oxidation and Coagulation

Architecture Civil Engineering Environment, 2010

A b s t r a c t The treatment of old municipal landfill leachate by Fenton oxidation, coagulation as well as coagulation combined with the Fenton oxidation was carried out on a laboratory scale. It has been found that organic pollutants in leachate could be suc cessfully removed by Fenton oxidation. The most advantageous dose of H 2O2 and Fe 2+ /H 2O2 ratio were 1350 mg/L and 0.2, respectively at pH 3 and reaction time of 45 minutes. In these operating conditions, the COD removal efficiency reached 61%. However, a 73.1% removal of COD was attained after 26 hours of Fenton oxidation. In coagulation process, the effi ciency was within the range of 39-45.8% using PIX as a coagulant at dose of 500 mg/L (pH 5 and 30 min of reaction time). The best result of COD removal (65.3%) was obtained in the combined treatment system including a coagulation process, followed by a Fenton oxidation. In this case, COD removal by coagulation was 45.8% while by Fenton oxidation only 19.5%. Therefore more...

Landfill Leachate Treatment by Coagulation and Flocculation Process

The leachate is a highly contaminant water hence it needs to be treated. The main aims of this research were to determine the Chemical oxygen demand (COD) concentration and heavy metals (zinc, chromium, lead, cadmium and nickel) in leachate in landfill area. The pollutants were analyzed using coagulation and flocculation process. The coagulants used were the aluminum sulphate (alum) and ferric chloride. The jar test apparatus were employed for the removal of pollutants. The experiments were carried out by varying the dosage of coagulants. The optimum pH level and the dosage level are also found as 8.5 and 3 g/l for ferric chloride and for alum 10.5 and 1.5 g/l. The alum is found to be efficient in the removal of heavy metals and ferric chloride for COD.

Diagnosis of leachate from a closed landfill, impact on the soil and treatment by coagulation flocculation with alginate and ferric chloride

DESALINATION AND WATER TREATMENT, 2020

This aim of study is to assess the diagnosis of leachate impacts on the soil of the closed landfill of the city of Mohammedia for several years and the treatment of these releases by coagulation-flocculation with a liquid effluent rich in FeCl 3 rejected by a company of steel (Maghreb STEEL) and also by alginate produced less expensive. Indeed, the leachate generated from closed dumping site at MESBAHIATE (Mohammedia, Morocco) was investigated. This leachate is characterized by a high chemical oxygen demand (COD) content which varies around 3,000 mg/L, a Kjeldahl total nitrogen concentration varying around 1,500 mg/L whereas the content in ammonium has a concentration of 960 mg/L. In addition, the BOD 5 /COD ratio is much less than 0.2, which indicates that the organic matter is not easily biodegradable, and subsequently justifies the use of physico-chemical treatments such as coagulation-flocculation. In order to monitor the leachate treatment by coagulation flocculation, several parameters were analyzed including: the turbidity, the COD, and the volume of the sludge decanted. The results showed that coagulation-flocculation by ferric chloride and alginate were very effective for reducing turbidity. This reduction reaches 95% and 86% for FeCl 3 and Alginate, respectively. The removal of COD by FeCl 3 30% and Alginate showed yields of 67% and 60%, respectively at optimal concentrations of 120 and 2,500 mg/L, respectively, for Alginate and FeCl 3 30%.

Reduction of COD and turbidity in leachates through coagulation-adsorption

2020

Department of Civil Engineering, National Institute of Technology, Manipur-795004<br> Email: albinoiit@gmail.com In this study, aluminium sulphate, ferric chloride and polyaluminium chloride coagulants were employed for reduction of organic colloids through cogulation-floculation and then adsorption using Parkia Speciosa (Petai) pods activated carbon for removal of dissolved ions from leachate. Polyaluminium chloride showed maximum turbidity reduction of 93.25% and 96.80% at optimum pH 4 for fresh and stabilized leachate respectively as compared to that of aluminium sulphate and ferric chloride with turbidity removals ranging from 70% to 91% for both types of leachate. The optimum doses of aluminium sulphate, ferric chloride and polyaluminium chloride for fresh leachate were 8 g/L with corresponding COD removals of 80%, 90% and 75% respectively. However, for stabilized leachate COD reduction, polyaluminium chloride and ferric chloride exhibits the same removals of 77.78% using...

Study on Treatment of Leachate from Landfill

A study was the investigated based on the leachate treatment which one of the apply to the coagulation-flocculation and Fenton process in the sequences of our process. Two types of the coagulant used: (i) aluminum sulphate (alum) (ii) ferric chloride were using standard jar test apparatus. Result indicated that which one of the best removal of the process so that alum was the 60.44% removal of the organic efficiency at pH 4.5 and alum dosages 7000 mg/l and ferric chloride was the 58.21% of the removal of organic efficiency at pH 5 and ferric chloride dosages 6000 mg/l. Further treatment of the sequential process is the Fenton process. Fenton process is exhibit at pH 3-3.5 and optimized parameter of the Fenton process for the Fe +2 dosages 15000 mg/l and H 2 O 2 dosages 30000 mg/l, H 2 O 2 /Fe +2 = 2.0, total reaction time 1 hr. After the Fenton process was the 82.54 % removal of the COD, and overall % of the COD removal efficiency is 92.0% removal.

Different treatment strategies for highly polluted landfill leachate in developing countries

Waste Management

The aim of this research was to determine appropriate treatment technique for effective treatment of heavily polluted landfill leachate. We accomplished several treatment experiments: (i) aerobic biological treatment, (ii) chemical coagulation, (iii) advanced oxidation process (AOP) and (iv) several combined treatment strategies. Efficiency of these treatment procedures were monitored by analysing COD and colour removal. Leachate used for this study was taken from Matuail landfill site at Dhaka city. With extended aeration process which is currently used in Matuail landfill site for leachate treatment, maximum COD and colour removal of 36% and 20%, respectively could be achieved with optimum retention period of 7 days. With optimum aluminium sulphate dose of 15,000 mg/L and pH value of 7.0, maximum COD and colour removals of 34% and 66%, respectively were observed by using chemical coagulation. With optimum pH of 5.0 and optimum dosages of reagents having H 2 O 2 /Fe 2+ molar ratio of 1.3 the highest removal of COD and colour were found 68% and 87%, respectively with sludge production of 55%. Fenton treatment which is an advanced oxidation process was the most successful between these three separate treatment procedures. Among the combined treatment options performed, extended aeration followed by Fenton method was the most suitable one.