Levels of polychlorinated dibenzo-p-dioxins and dibenzofurans in China and chemometric analysis of potential emission sources (original) (raw)
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Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/F) were analyzed in surface sediments and top soils collected from 30 sites in Daliao River Basin. The concentrations of PCDD/F ranged from 0.28 to 29.01ng TEQ kg−1 dw (mean value, 7.45ng TEQkg−1dw) in sediments, and from 0.31 to 53.05ng TEQkg−1dw (mean value, 7.00ng TEQkg−1dw) in soils. PCDD/F pollution in sediments from the mid- and
Chemosphere, 2008
The emission inventory and strategy for reducing unintentionally formed products is a very complex and difficult part of the NIP. In this paper, we analyzed the potential sources of polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans in China and calculated their possible emissions. We included municipal solid waste incineration, hazardous and medical waste incineration, pulp bleaching, sodium pentachlorophenate production and usage, illegal electrical and electronic waste (''e-waste") recycling, and ferrous and non-ferrous metal production, and prepared a preliminary analysis of dioxin emissions in China. The results show that ferrous metal production (104.2-6648.3 g TEQ), non-ferrous metal production (2.6-3389.8 g TEQ), and sodium pentachlorophenate production and usage (120-368.0 g TEQ) should be major potential sources of dioxins and furans. Moreover, municipal solid waste and hazardous and medical waste incineration (35.5 g TEQ) should also be considered high priority sources owing to a rapidly increasing incineration ratio anticipated for the near future.
Chemosphere, 2007
The pollution status of polychlorinated dibenzo-p-dioxins, dibenzofurans (PCDD/Fs) and polychlorinated biphenyls (PCBs) in the sediments of Haihe River, which is the most polluted among the seven largest basins in China, Dagu Drainage River flowing through a chemical industry zone, and two other rivers flowing into Bohai Sea in Tianjin City, China were investigated. The concentrations of PCDD/Fs and PCBs in the sediments from the mainstream of Haihe River were 1.3-26 pg I-TEQ g À1 dry weight (dw) and 0.07-0.54 pg TEQ g À1 dw, respectively. Heavy PCDD/Fs and PCBs pollution, with 1264 pg I-TEQ g À1 dw and 21 pg TEQ g À1 dw, was found in sediment from Dagu Drainage River. The congener profiles of PCDD/Fs indicated that the principal contamination source was the production of pentachlorophenol (PCP) or PCP-Na in this area. The correlation between PCDD/Fs or PCBs and total organic matter (TOM) showed that PCDD/Fs or PCBs were independent on TOM.
Chemosphere, 2010
The levels of polychlorinated dibenzo-p-dioxin and dibenzofuran (PCDD/PCDFs), and dioxin-like polychlorinated biphenyls (DL-PCBs) were determined in sediment samples from Can Gio, South Vietnam, and Osaka, Japan. Can Gio is known for the defoliation of its mangrove forests by aerial spraying with Agent Orange during the Vietnam War, whereas Osaka is renowned for a PCDD/PCDF pollution accident at a municipal solid-waste incinerator. For comparison, we also analyzed PCDD/PCDFs and DL-PCBs in sediment samples from Hue and Hanoi, Vietnam. The toxic equivalent quantity (TEQ) values in Can Gio were as high as those in Hue, Hanoi, and suburban areas of Osaka, but much lower than those in urban areas of Osaka. The proportion of the World Health Organization (WHO)-TEQ value contributed by 2,3,7,8-tetrachlorinated dibenzo-p-dioxin (TCDD) in Can Gio was approximately 30%, higher than the values in the other sample areas. These data suggest that residual sedimentary TCDD that originated from aerial spraying of Agent Orange occur in only low concentrations in Can Gio. The main contributors to WHO-TEQ values in Can Gio are natural sources, as in Hue. In contrast, commercial PCBs are the dominant contributors to WHO-TEQ values in Hanoi. In Osaka, agrochemicals used in rice cultivation, the incineration of solid waste, and commercial PCBs equally contributed to WHO-TEQ values at suburban locations. The dumping of incinerator-related materials and/or the inadequate management of commercial PCBs have resulted in significantly elevated WHO-TEQ values of 240-370 ng kg -1 dw at urban locations in Osaka.
Analysis of Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans in Soil and Sediment
Archives of Industrial Hygiene and Toxicology, 2000
Twenty-one fresh water samples were taken from reservoirs, wells and drinking water treatment plants in Taiwan for measurement of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) concentrations. Due to low concentration of PCDD/Fs, water samples (400-1000 L) were collected by using the on-site large volume pre-concentration system and analyzed by high resolution gas chromatography (HRGC)/high resolution mass spectrometer (HRMS). Different characteristics of dioxin profiles in surface water and groundwater are observed. The PCDD/F concentrations in fresh water samples varied from 0.001 to 0.265 pg WHO 98 -TEQ/L which are lower than the standard (12 pg WHO 98 -TEQ/L) set by the Taiwan Environmental Protection Administration (TEPA) for drinking water. Only a small fraction (<5%) of the total PCDD/F concentration in fresh water samples was water-soluble. As a result of their hydrophobicity, PCDD/Fs are effectively removed along with suspended solid via the water treatment process (average 98% removal efficiency).
Chemosphere, 1998
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDDs/PCDFs) in sediment and soil from a freshwater lake area were congener-specifically determined. The obtained data were examined to estimate the major origins of these compounds, with the aid of principal component analysis (PCA). Four major principal components (PCs) were obtained, and three of them were attributed to PCDDs/PCDFs in the atmosphere, in a diphenyl ether herbicide and in pentachlorophenol, based on congener-specific comparisons with references. One PC remained unattributed. These four were interpreted as the major origins of PCDDsRCDFs in the area. The relative intluence of the origins was also investigated.
Journal of Hazardous Materials, 2010
Concentrations of polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in sediments from Bohai Sea and Yellow Sea coastal waters and lakes in Shandong Peninsula were determined. The total PCB concentrations of the measured 50 congeners ( 50PCBs) in the sediments ranged from 273.7 to 644.5 pg g −1 dw (dry weight). The PCB congener profiles in the lacustrine sediments were different from those in the marine sediments. TriCBs and TetraCBs were the dominant homologues in marine sediments, whereas in the sediments from the Nansi Lakes, contributions of PCB homologues were similar. The total concentrations of 2,3,7,8-PCDD/Fs ranged from 6.2 to 27.4 pg g −1 dw. The congener profiles of 2,3,7,8-sustituted PCDD/Fs for the sediments were generally similar for both the lakes and the coastal sea areas in Shandong Peninsula. They were characterized by high OCDD, followed by 1,2,3,4,6,7,8-HpCDD and OCDF. The congener profiles of PCDD/Fs in the sediments were consistent with the profiles of main dominant PCDD/Fs in pentachlorophenol and sodium pentachlorophenate products in China. PCDD/F-TEQ ranged from 0.11 to 0.80 pg TEQ g −1 dw. The dioxinlike PCB-TEQ had concentrations ranging from 0.03 to 0.08 pg TEQ g −1 dw, mainly from PCB126. PCBs and PCDD/Fs concentrations found in the sediments were from background to low polluted levels.