Spinning and Processing Continuous Yarns from 4-Inch Wafer Scale Super-Aligned Carbon Nanotube Arrays (original) (raw)
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Carbon nanotubes (CNTs), a dependable allotrope of carbon, are foreseen to lead technology further to its reach. Also, the most researched carbon allotrope in its form. Drawable CNTs have recently unraveled numerous possible applications utilizing vertically aligned CNTs also termed as "CNT forest." In recent years, the rapid growth of dense and long carbon nanotube arrays has succeeded in surpassing its challenges by synthesizing dense and long CNT arrays. Length, density, and drawability tuning in the synthesis of CNT arrays have always been a complex issue lately. However, numerous research techniques emerged focusing on length and density control. Hence, this book chapter aids in unveiling the current achievements in the growth of dense and long CNT arrays and their application in spinning threads or CNT yarns with numerous other possible applications.
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The effects of processing conditions and apparent nanotube length on properties are investigated for carbon nanotube yarns obtained by solid-state drawing of an aerogel from a forest of multi-walled carbon nanotubes. Investigation of twist, false twist, liquid densification and combination methods for converting the drawn aerogel into dense yarn show that permanent twist is not needed for obtaining useful mechanical properties when nanotube lengths are long compared with nanotube diameters. Average mechanical strengths of 800 MPa were obtained for polymer-free twist-spun multi-walled carbon nanotube (MWNT) yarns and average mechanical strengths of 1040 MPa were obtained for MWNT yarns infiltrated with 10 wt% polystyrene solution. Strategies for increasing the mechanical properties are suggested based on analysis of intra-wall, intra-bundle and inter-bundle stress transfer.