Martensitic phase transformation of Cu-Zn-Al alloy, induced by cold rolling deformation (original) (raw)

2013, Acta Fracturae

The purpose of this paper is to study the phase transformation induced by the cold rolling of a Cu- Zn-Al alloy fabricated in our laboratories. Flat specimens were made from the alloy. They were subsequently heat treated at 850°C/20 min, quenched in water at 100°C, treated at 320°C/30 min, quenched in water at 100°C, cooled in air up to room temperature. To correlate the microstructure variations with the entity of the imposed deformation, the samples were cold rolled selectively (each 2.5%) up to 15% of deformation. On each cold rolled sample, the microstructures were investigated by LOM and XRD. The deformation has contributed to β3 (L21) ordering of the structure and to occur the martensitic transformation. The martensite obtained is the M18R type. This result shows that the parameter which most influences the type of obtainable martensite is determined by the order of the parent phase. During testing it was found that the martensite enucleates in appreciable quantities even at a level of deformation of 2.5% of the specimen. An increase of the martensite up to a deformation of 15% was observed. It has not been possible to continue beyond this level of deformation, due to the presence of transgranular cracks.

Effect of cold rolling and annealing temperature to the characteristics of α + β' phases in Cu-29.5Zn-2.5Al alloy produced by gravity casting

Journal of Mining and Metallurgy, Section B: Metallurgy

Al-brass alloys (Cu29.5Zn2.5Al wt. %) were produced by gravity casting and homogenized at 800?C for 2 h, resulting in a binary phase morphology identified as cubic ? and martensitic ?? phases through X-ray diffraction (XRD). Samples were then subsequently cold rolled and annealed at 150, 300, 400, and 600?C for 30 minutes. Visible traces of slip, intersecting slip bands, and shear bands were observed in microstructure images of the samples after each progressive deformation stage. Deformation-induced martensites were present after 20 % cold rolling. Higher thickness reduction resulted in simultaneous strain hardening of the phases. Low temperature annealing slightly increased microhardness, of both ? and ??, due to the formation of precipitates. SEM-EDX analysis showed that no solute segregation was found in annealed samples. Annealing at higher temperature resulted in conventional softening. Recrystallized equiaxed ?? phase grains were visible after annealing at 600?C.

Heating rate effects on reverse martensitic transformation in a Cu – Zn – Al shape memory alloy

International Journal of Materials Research, 2011

Different fragments of martensitic Cu-14.86 Zn-5.81 Al-0.5 Fe (mass.%) shape memory alloy were subjected to heating, up to 453 K, with different rates ranging from 1.66 ×10−2 K s−1 to 54.6 × 1.66 × 10−2 K s−1, performed by means of a differential scanning calorimeter. In all cases, during heating, an endothermic peak was observed which was associated with the martensite reversion to parent phase. By means of the differential scanning calorimeter charts the critical transformation temperatures of martensite reversion were determined using the tangent method. The effects of heating rate were evaluated from the point of view: (i) of variation tendencies of critical transformation temperatures; (ii) of deviations of experimental values from linear fit and extrapolation to zero heating rate; and (iii) of corroborating morphological changes of martensite (sub)plates with heat flow variation particularities. The results prove that there is an obvious tendency of critical transformation tem...

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