A combined diffraction (XRD, electron and neutron) and electrical study of Na 3MoO 3F 3 (original) (raw)

2003, Journal of Solid State Chemistry

Na 3 MoO 3 F 3 , a member of the A 2 BM VI O 3 F 3 family of elpasolite-related oxyfluorides, has been prepared by the reaction of NaF with MoO 3 at 650 C. It is shown by a combined X-ray, electron and neutron diffraction study, that the true symmetry of Na 3 MoO 3 F 3 is not monoclinic (pseudo-orthorhombic) as previously reported but instead triclinic (metrically rhombohedral) P1:

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