Multi-Phase Carbon Fiber-MWNT/Epoxy Composites (original) (raw)
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Nano-engineered composites: interlayer carbon nanotubes effect
Materials Research, 2013
The concept of carbon nanotube interlayer was successfully introduced to carbon fiber/epoxy composites. This new hybrid laminated composites was characterized by Raman spectroscopy, X-ray diffraction, scanning electron microscopy and tensile tests. An increase on peak stress close to 85% was witnessed when CNTs interlayer with 206.30 mg was placed to carbon fiber/epoxy laminates. The failure mechanisms are associated to CNTs distribution between and around carbon fibers. These CNTs are also responsible for crack bridging formation and the increase on peak stress. Initial stiffness is strongly affected by the CNT interlayer, however, changes on stiffness is associated to changes on nano/micro-structure due to damage. Three different behaviors can be described, i.e. for interlayers with ≈ 60 mg of CNT the failure mode is based on cracks between and around carbon fibers, while for interlayers with CNT contents between 136 mg and 185 mg cracks were spotted on fibers and inside the CNT/matrix mix. Finally, the third failure mechanism is based on carbon fiber breakage, as a strong interface between CNT/matrix mix and carbon fibers is observed.
A novel class of multiscale epoxy composites was developed containing carbon fibers (CFs) and multiwalled carbon nanotubes (MWCNTs) to explore their mutual effect on the mechanical performance of composites. The loading of CFs in composites was kept constant at 60 wt%, while the contents of MWCNTs were increased from 0.5 wt% to 2.0 wt%. MWCNTs were functionalized through acid treatment before incorporating into epoxy matrix to promote dispersion quality. The developed composites were characterized microstructurally by scanning electron microscopy and mechanically by tensile, flexural, edgewise compression, and hardness tests. Homogeneous dispersion of MWCNTs was observed until their loading of 1.5 wt%, which enhanced the mechanical performance of composites. Hardness increased up to 47% while tensile, flexural, and edgewise compressive moduli increased to 40%, 16.3%, and 164%, respectively. Moreover, tensile, flexural, and edgewise compressive strengths showed rises of 45%, 15.2%, and 43%, respectively. The fracture strain increased in both the tensile and flexural tests while it decreased in edgewise compressive tests. Increasing the MWCNTs in composites to 2.0 wt% produced their agglomerates and reversed the rising trend in mechanical properties. POLYM. COMPOS.,
Composites Science and Technology, 2011
Carbon nanotubes (CNT) in their various forms have great potential for use in the development of multifunctional multiscale laminated composites due to their unique geometry and properties. Recent advancements in the development of CNT hierarchical composites have mostly focused on multi-walled carbon nanotubes (MWCNT). In this work, single-walled carbon nanotubes (SWCNT) were used to develop nano-modified carbon fiber/epoxy laminates. A functionalization technique based on reduced SWCNT was employed to improve dispersion and epoxy resin-nanotube interaction. A commercial prepregging unit was then used to impregnate unidirectional carbon fiber tape with a modified epoxy system containing 0.1 wt% functionalized SWCNT. Impact and compression-after-impact (CAI) tests, Mode I interlaminar fracture toughness and Mode II interlaminar fracture toughness tests were performed on laminates with and without SWCNT. It was found that incorporation of 0.1 wt% of SWCNT resulted in a 5% reduction of the area of impact damage, a 3.5% increase in CAI strength, a 13% increase in Mode I fracture toughness, and 28% increase in Mode II interlaminar fracture toughness. A comparison between the results of this work and literature results on MWCNT-modified laminated composites suggests that SWCNT, at similar loadings, are more effective in enhancing the mechanical performance of traditional laminated composites.
Carbon fiber reinforced epoxy composite laminates, with strategically incorporated fluorine functionalized carbon nanotubes (f-CNTs) at 0.2, 0.3 and 0.5 weight percent (wt.%), are studied for improvements in tensile strength and stiffness and durability under both tension-tension (R = +0.1) and tension-compression (R = À0.1) cyclic loadings, and then compared to the neat (0.0 wt.% CNTs) composite laminate material. To develop the nanocomposite laminates, a spraying technology was used to deposit nanotubes on both sides of each four-harness satin weave carbon fiber fabric piece for the 12 ply laminate lay up. For these experimental studies the carbon fiber reinforced epoxy laminates were fabricated using a heated vacuum assisted resin transfer molding (H-VARTM Ò ) method followed by a 2 soak curing cycle. The f-CNTs toughened the epoxy resin-fiber interfaces to mitigate the evolution of fiber/fabric-matrix interfacial cracking and delamination under both static and cyclic loadings. As a consequence, significant improvements in the mechanical properties of tensile strength, stiffness and resistance to failure due to cyclic loadings resulted for this carbon fiber reinforced epoxy composite laminate.
Inter laminar failure behavior in laminate carbon nanotubes-based polymer composites
Journal of Composite Materials, 2018
Delamination progressive in carbon nanotubes reinforced composites under applied Short Beam Shear test was studied. Experimental characterization was carried out using ASTM D2344 standard norms for different carbon nanotubes mass fractions ranging from 0 to 4%. Failure modes and the delamination were experimentally characterized by scanning electron microscopy and Kayence microscopy to assess the failure behavior. The numerical model was created under ABAQUS software based on the cohesive zone models. The numerical model was formulated according to the damage mechanics. In these models, the cohesive interaction was implanted between elements of each fabric ply to control the initiation and the propagation of the delamination for different carbon nanotubes fractions. The force–displacement curves vs. carbon nanotubes added were obtained for the numerical model and shown to be in good agreement with the experimental data. The effect of carbon nanotubes on the progressive delamination ...
2012
We investigated the effect of the inclusion of carbon nanotubes (CNT) on the mechanical properties and wear behavior of epoxy/carbon and epoxy/carbon-aramid composites in this study. Epoxy/carbon and epoxy/carbonaramid composites with 0 wt.% CNT and 0.3 wt.% CNT were manufactured by RTM, amino functionalized multi-walled CNT (MWCNT) were used to modify the matrix. Tensile, compression, two rail shear, Charpy impact tests and Pin On Disc (POD) were performed on the four composites. The EP/CAF composites showed better impact resistance than the ones containing carbon woven. The addition of CNTs improves the shear modulus in 5% for EP/CF composites and 6% for EP/CAF. The results also show that the dynamic friction coefficient is independent of the CNT content, and the specific wear rate shows no improvement with the selected test parameters.
2016
ARTICLE INFORMATION ABSTRACT Original Research Paper Received 13 January 2016 Accepted 04 February 2016 Available Online 02 March 2016 In this research, the influence of adding carbon nanotubes on the tensile and the mode I interlaminar fracture of glass-fiber-epoxy laminated composite has been experimentally studied. For this purpose, the hybrid glass-fiber-epoxy-nanotube laminated composites which have 18 fiber-glass plain-weave layers were manufactured by hand lay-up method. The epoxy resin system is made of Epon828 resin with Epikure F205 as the curing agent. The multi-walled carbon nanotube (MWCNTs) modified with hydroxide (-COOH) is also dispersed into the epoxy system as a reinforcement in a 0%, 0.1%, 0.5% and 1% ratio in weight with respect to the matrix. In addition, the tensile nano-resin and hybrid nanocomposite specimen were produced. The results of the tensile test of nano-matrixes indicate that the maximum change in Young's modulus, ultimate strength and fracture t...
Journal of Nanomaterials, 2014
The present paper discusses the key issues of carbon nanotube (CNT) dispersion and effect of functionalisation on the mechanical properties of multiscale carbon epoxy composites. In this study, CNTs were added in epoxy matrix and further reinforced with carbon fibres. Predetermined amounts of optimally amine functionalised CNTs were dispersed in epoxy matrix, and unidirectional carbon fiber laminates were produced. The effect of the presence of CNTs (1.0 wt%) in the resin was reflected by pronounced increase in Young's modulus, inter-laminar shear strength, and flexural modulus by 51.46%, 39.62%, and 38.04%, respectively. However, 1.5 wt% CNT loading in epoxy resin decreased the overall properties of the three-phase composites. A combination of Halpin-Tsai equations and micromechanics modeling approach was also used to evaluate the mechanical properties of multiscale composites and the differences between the predicted and experimental values are reported. These multiscale composites are likely to be used for potential missile and aerospace structural applications.
Composite Interfaces, 2018
Functionalized multiwalled carbon nanotubes were successfully deposited on carbon fibers using four different techniques including dip coating, hand layup, spray up and electrophoretic deposition (EPD). A uniform coating of nanotubes was achieved from EPD in comparison to other coating techniques. Later nanotube-coated fibers by EPD were introduced in epoxy resin to investigate interfacial mechanical properties of the developed hierarchical composites by vacuum bagging technique. The increases in flexural and interlaminar shear properties up to 15% and 18% were observed in composites containing nanotube-coated carbon fibers than composites with virgin carbon fibers, respectively. Microscopic observation revealed the proper impregnation of multiscale reinforcements, i.e., carbon fibers and carbon nanotubes, in resin along with the modification of fiber/matrix interface due to the presence of nanotubes at interface. Finally, the mechanisms for improved mechanical properties were identified along with the presentation of a schematic model for better understanding of the improved performance of hierarchical composite after depositing uniformly dispersed nanotubes on carbon fibers.
Russian Journal of Applied Chemistry, 2016
Effect of the catalyst composition on the structure of nanotubes layers obtained on the surface of carbon nanofi bers was studied. We found the preliminary functionalization of the surface of carbon fi bers to affect the coating uniformity and the thickness of synthesized nanotube layer. We determined the optimal surface concentration of the catalyst (Fe-Co) which provides uniform layer of nanotubes on the surface of carbon fi bers. The effect of modifi cation of the surface of carbon fi bers with multi-walled carbon nanotubes on the mechanical properties of carbon fi ber-epoxy resin composites was examined. The modifi cation of the carbon fi bers with multi-walled carbon nanotubes were shown to increase the fl exural modulus and the fl exural strength.