Atom transfer radical cyclisations of activated and unactivated N-allylhaloacetamides and N-homoallylhaloacetamides using chiral and non-chiral copper complexes (original) (raw)

Journal of the Chemical Society, Perkin Transactions 1, 2000

Abstract

In recent years, transition metal mediated free radical processes have gained in importance.1 In particular the atom transfer radical cyclisation reactions (ATRC) of 2,2,2-trichlorinated carbonyl compounds have been reported with a range of metal catalysts, eg RuCl 2 (PPh 3 ) 3 ,2 ...

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