Induced Superconductivity in Graphene Grown on Rhenium (original) (raw)
Related papers
2D Materials, 2020
Graphene holds promises for exploring exotic superconductivity with Dirac-like fermions. Making graphene a superconductor at large scales is however a long-lasting challenge. A possible solution relies on epitaxially-grown graphene, using a superconducting substrate. Such substrates are scarce, and usually destroy the Dirac character of the electronic band structure. Using electron diffraction (reflection high-energy, and low-energy), scanning tunneling microscopy and spectroscopy, atomic force microscopy, angle-resolved photoemission spectroscopy, Raman spectroscopy, and density functional theory calculations, we introduce a strategy to induce superconductivity in epitaxial graphene via a remote proximity effect, from the rhenium substrate through an intercalated gold layer. Weak graphene-Au interaction, contrasting with the strong undesired graphene-Re interaction, is demonstrated by a reduced graphene corrugation, an increased distance between graphene and the underlying metal, a linear electronic dispersion and a characteristic vibrational signature, both latter features revealing also a slight p doping of graphene. We also reveal that the main shortcoming of the intercalation approach to proximity superconductivity is the creation of a high density of point defects in graphene (10 14 cm −2). Finally, we demonstrate remote proximity superconductivity in graphene/Au/Re(0001), at low temperature.
2020
Graphene holds promises for exploring exotic superconductivity with Dirac-like fermions. Making graphene a superconductor at large scales is however a long-lasting challenge. A possible solution relies on epitaxially-grown graphene, using a superconducting substrate. Such substrates are scarce, and usually destroy the Dirac character of the electronic band structure. Using electron diffraction (reflection high-energy, and low-energy), scanning tunneling microscopy and spectroscopy, atomic force microscopy, angle-resolved photoemission spectroscopy, Raman spectroscopy, and density functional theory calculations, we introduce a strategy to induce superconductivity in epitaxial graphene viaviavia a remote proximity effect, from the rhenium substrate through an intercalated gold layer. Weak graphene-Au interaction, contrasting with the strong undesired graphene-Re interaction, is demonstrated by a reduced graphene corrugation, an increased distance between graphene and the underlying metal,...
Unconventional Superconductivity in Semiconductor Artificial Graphene
arXiv: Superconductivity, 2019
Unconventional superconductivity featuring large pairing energies has attracted immense interest, yet tractable microscopic theories have proven elusive. A major breakthrough has been the advent of twisted bilayer graphene (TBG), which serves as a simple model system to 'look under the hood' of unconventional superconductivity. We propose a new model, within current experimental reach, to investigate the microscopics of strong-binding superconductivity. Our proposed device is semiconductor artificial graphene (AG), a two dimensional electron gas overlaid with a periodic potential (superlattice). We demonstrate a new mechanism for superconductivity that originates solely from the repulsive Coulomb interaction. The superlattice promotes certain interactions, which are antiscreened, cause attractive ppp-wave pairing and - in contrast to graphene - can be strongly enhanced through device engineering. The strength of the pairing energy is similar to TBG, and we find within the ac...
Scanning tunneling spectroscopy of proximity superconductivity in epitaxial multilayer graphene
Physical Review B, 2016
We report on spatial measurements of the superconducting proximity effect in epitaxial graphene induced by a graphene-superconductor interface. Superconducting aluminum films were grown on epitaxial multilayer graphene on SiC. The aluminum films were discontinuous with networks of trenches in the film morphology reaching down to exposed graphene terraces. Scanning tunneling spectra measured on the graphene terraces show a clear decay of the superconducting energy gap with increasing separation from the graphene-aluminum edges. The spectra were well described by Bardeen-Cooper-Schrieffer (BCS) theory. The decay length for the superconducting energy gap in graphene was determined to be greater than 400 nm. Deviations in the exponentially decaying energy gap were also observed on a much smaller length scale of tens of nanometers.
Subgap states in two-dimensional spectroscopy of graphene-based superconducting hybrid junctions
Physical review, 2019
The two-dimensional nature of graphene makes it an ideal platform to explore proximity-induced unconventional planar superconductivity and the possibility of topological superconductivity. Using Green's functions techniques, we study the transport properties of a finite size ballistic graphene layer placed between a normal state electrode and a graphene lead with proximity-induced unconventional superconductivity. Our microscopic description of such a junction allows us to consider the effect of edge states in the graphene layer and the imperfect coupling to the electrodes. The tunnel conductance through the junction and the spectral density of states feature a rich interplay between graphene's edge states, interface bound states formed at the graphene-superconductor junction, Fabry-Pérot resonances originated from the finite size of the graphene layer, and the characteristic Andreev surface states of unconventional superconductors. Within our analytical formalism, we identify the separate contribution from each of these subgap states to the conductance and density of states. Our results show that graphene provides an advisable tool to determine experimentally the pairing symmetry of proximity-induced unconventional superconductivity.
Enhancement of superconductivity upon reduction of carrier density in proximitized graphene
Physical review, 2022
The superconducting transition temperature (Tc) of a single layer graphene coupled to an Indium oxide (InO) film, a low carrier-density superconductor, is found to increase with decreasing carrier density and is largest close to the average charge neutrality point in graphene. Such an effect is very surprising in conventional BCS superconductors. We study this phenomenon both experimentally and theoretically. Our analysis suggests that the InO film induces random electron and hole-doped puddles in the graphene. The Josephson effect across these regions of opposite polarity enhances the Josephson coupling between the superconducting clusters in InO, along with the overall Tc of the bilayer heterostructure. This enhancement is most effective when the chemical potential of the system is tuned between the charge neutrality points of the electron and hole-doped regions.
Gate-Tunable Superconducting-Insulating Transition in Tin-Decorated Graphene
2012
Graphene 1 is a sturdy and chemically inert material exhibiting an exposed two-dimensional electron gas of high mobility. These combined properties enable the design of graphene composites, based either on covalent 2 or non-covalent 3 coupling of adsorbates, or on stacked and multilayered heterostructures 4 . These systems have shown tunable electronic properties such as bandgap engineering 3 , reversible metal-insulating transition 2,4 or supramolecular spintronics 5 . Tunable superconductivity is expected as well 6 , but experimental realization is lacking. Here, we show experiments based on metal-graphene hybrid composites, enabling the tunable proximity coupling of an array of superconducting nanoparticles of tin onto a macroscopic graphene sheet. This material allows full electrical control of the superconductivity down to a strongly insulating state at low temperature. The observed gate control of superconductivity results from the combination of a proximity-induced superconductivity generated by the metallic nanoparticle array with the two-dimensional and tunable metallicity of graphene. The resulting hybrid material behaves, as a whole, like a granular superconductor showing universal transition threshold and localization of Cooper pairs in the insulating phase. This experiment sheds light on the emergence of superconductivity in inhomogeneous superconductors, and more generally, it demonstrates the potential of graphene as a versatile building block for the realization of superconducting materials.
Proximity-induced superconductivity in graphene
JETP Letters, 2008
We propose a way of making graphene superconductive by putting on it small superconductive islands which cover a tiny fraction of graphene area. We show that the critical temperature, Tc, can reach several Kelvins at the experimentally accessible range of parameters. At low temperatures, T ≪ Tc, and zero magnetic field, the density of states is characterized by a small gap Eg ≤ Tc resulting from the collective proximity effect. Transverse magnetic field Hg(T) ∝ Eg is expected to destroy the spectral gap driving graphene layer to a kind of a superconductive glass state. Melting of the glass state into a metal occurs at a higher field Hg2(T).
Kohn-Luttinger superconductivity in graphene
Physical Review B, 2008
We investigate the development of superconductivity in graphene when the Fermi level becomes close to one of the Van Hove singularities of the electron system. The origin of the pairing instability lies in the strong anisotropy of the e-e scattering at the Van Hove filling, which leads to a channel with attractive coupling when making the projection of the BCS vertex on the symmetry modes with nontrivial angular dependence along the Fermi line. We show that the scale of the superconducting instability may be pushed up to temperatures larger than 10 K, depending on the ability to tune the system to the proximity of the Van Hove singularity.
Electrical control of the superconducting-to-insulating transition in graphene–metal hybrids
Nature Materials, 2012
Graphene is a sturdy and chemically inert material exhibiting an exposed two-dimensional electron gas of high mobility. These combined properties enable the design of graphene composites, based either on covalent or non-covalent coupling of adsorbates, or on stacked and multilayered heterostructures. These systems have shown tunable electronic properties such as bandgap engineering, reversible metal-insulating transition or supramolecular spintronics. Tunable superconductivity is expected as well, but experimental realization is lacking. Here, we show experiments based on metal-graphene hybrid composites, enabling the tunable proximity coupling of an array of superconducting nanoparticles of tin onto a macroscopic graphene sheet. This material allows full electrical control of the superconductivity down to a strongly insulating state at low temperature. The observed gate control of superconductivity results from the combination of a proximity-induced superconductivity generated by the metallic nanoparticle array with the two-dimensional and tunable metallicity of graphene. The resulting hybrid material behaves, as a whole, like a granular superconductor showing universal transition threshold and localization of Cooper pairs in the insulating phase. This experiment sheds light on the emergence of superconductivity in inhomogeneous superconductors, and more generally, it demonstrates the potential of graphene as a versatile building block for the realization of superconducting materials.