Factors Influencing Hydride Formation in a Pd/TiO 2 Catalyst (original) (raw)
2006, Journal of Physical Chemistry B
A sample containing Pd nanoparticles deposited on TiO 2 was subjected to a series of different thermal pretreatments. The range of these treatments was selected to provide a palladium surface in a number of different states, including a form where TiO x overlayers had been formed. Experiments were conducted to determine how the state of the Pd surface influenced the formation of Pd hydride. The amount of hydrogen released during a temperature-programmed experiment was used to quantify the extent of Pd -hydride formation following room-temperature exposure to hydrogen. Samples were characterized by HAADF (highangle annular dark-field) electron microscopy with EDX (energy-dispersive X-ray) analysis and CO pulse chemisorption and FTIR (Fourier transform infrared spectroscopy) of adsorbed CO. The amount and the ease with which Pd -hydride was formed was found to be dependent on the metal surface area, the presence of titania overlayers, and the Pd surface roughness/defect concentration.
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