Colorimetric Quantification Methods for Peracetic Acid together with Hydrogen Peroxide for Water Disinfection Process Control (original) (raw)

Peracetic acid (PAA) water solutions is applied for disinfection of industry systems, food products and non-potable water. Commercially available peracetic acid is always supplied mixed with hydrogen peroxide (H2O2). H2O2 degrade slower than the peracetic acid which creates a need to quantify both peroxides separately to gauge the disinfection power of the solution and the residuals. Two combinations of colorimetric reactions are presented that allows simultaneous quantification at the mg·L−1 level used in disinfection liquids and water disinfection. The first dichromic reaction use titanium oxide oxalate (TiO-Ox) which only react with H2O2 followed by addition of N,N-diethyl-p-phenylenediamine with iodide (DPD/I−) and the concentrations are read by simultaneously measuring the absorbance at 400 and 515 nm. Limit of quantification (LOQ) and maximal concentration determined was 4.6 µg·L−1 and 2.5 mg·L−1 for PAA and 9.1 µg·L−1 and 5 mg·L−1 for H2O2. The two color reactions didn’t inte...