SrMgP2O7 (original) (raw)

Acta Crystallographica Section E-structure Reports Online, 2001

Abstract

ABSTRACT Crystals of SrMgP2O7 are monoclinic, space group P21/n, with a 5.3046(8), b 8.3053(13), c 12.700(2) Å, β 90.502(3)°; Z = 4, dc = 3.394; R = 0.036, Rw(F2) = 0.071 for 1798 reflections. The structure belongs to the α-Ca2P2O7 isotypical pyrophosphate series SrMP2O7 (M = Cr, Mn, Fe, Co, Ni, Cu, Zn). MgII atoms occupy square-pyramidal coordination and are isolated in the structure. [MgO5] units and the [P2O7] groups form a three-dimensional framework with channels along [100] and [010], in which are located Sr2+ ions. [on SciFinder(R)]

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