10.5937/mmeb1403153j = Technological investigations of sulphide oxidation from flotation tailings in order to increase the degree of copper leaching (original) (raw)
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Metallurgical and Materials Engineering, 2020
This work aimed to investigate optimal leaching technology for copper extraction from old flotation tailings of the Copper Mine Bor. The leaching degree of copper after leaching with sulphuric acid at 80 °C was 50%, the maximal leaching degree was achieved after 30 minutes. Then, old flotation tailings were leached with adapted moderately thermophilic acidophilic bacteria in a bioreactor at 40 °C. Maximal leaching degree of 84% was achieved after nine days of the experiment. The third leaching experiment was conducted with biogenic lixiviant obtained by bacterial oxidation of the ferrous iron (concentration of Fe3+ 1300 mgL-1, pH 2.14). Biogenic lixiviant with ferric sulphate was then used in the leaching experiment at 80 °C. Maximal leaching degree was 78%, and it was achieved after five minutes. Results of the leaching experiments show that the most efficient technology for copper recovery from the old flotation tailings of the Copper Mine Bor was leaching with biogenic lixiviant.
Journal of Mining and Metallurgy, Section B: Metallurgy
The ancient flotation tailings from Lefke, Cyprus, have a potential for non-ferrous metals such as cobalt and copper from more than 9.5 million tons of reserves containing 0.38% Cu, 0.032% Co, and 22.6% Fe. Recovery of cobalt and copper from these tailings can provide great benefits from economic and environmental perspectives. While the ancient tailings were kept long time in storage in dumps, the characteristics of the material has become different from the common Co and Cu bearing ores. In order to extract these valuable metals, a process involving combination of roasting and leaching was applied in this study. Since this process responded to recovery to some extent, an innovative technique of using Na2SO4 as a promoter during roasting was proposed. Utilizing of Na2SO4 did not provide only higher metal extractions, but also resulted in high selectivity. In the scope of the study, following the determination of the mineralogy and chemical composition of the tailings, certain proce...
Mining and Metallurgy Engineering Bor, 2014
This work presents the study of copper extraction from smelter slag, which is subjected to sulphating. Sulphating of slag was performed by pyrite concentrate or flotation tailings at temperatures from 500 to 650°C, and the resulting calcine was leached with water. The results showed that maximum copper leaching (70-73%) is obtained from calcine, obtained by two-and three hour sulphating at 550 o C. The process is selective since only 3-5% of iron is leached. In addition to sulphating temperature, it was found that a great effect on copper leaching has the pyrite/flotation tailings: ratio. The best results were achieved by sulphating of 5.00 g slag with 2.00 g of pyrite or 3.00 g of tailings.
Influence of liberation of sulphide minerals on flotation of sedimentary copper ore
2017
Ore liberation is one of the most important parameter in mineral processing, especially in flotation. To separate the valuable components from gangue minerals, it is necessary to liberate one from others. It is achieve primarily through crushing and grinding. These stages are one of the most expensive of mineral production. It is important to determine the adequate mineral liberation which would result in huge savings in the overall cost of flotation plant. The aim of the paper was the analysis of the influence of milling time on the laboratory flotation of the copper ore from stratiform Polish deposit. Three different milling time of copper ore in laboratory ball mill was applied. The flotation results were presented as the recovery-recovery and grade-recovery upgrading curves. The liberation of sulphides and the particle size of sulphides in flotation product were analysed and compared.
Hemijska industrija, 2014
Copper mine "Cerovo"- East Serbia as well as the other ore bodies in its vicinity contain a significant amount of oxide copper minerals in their uper layers (>40%). Processing of such mixed ores by the existing concentration technologies leads to a substantial copper losses (<60%). Reduction of "oxide copper", by acid leaching prior the flotation concentration, can increase the overall copper efficiency up to more than 70% in the single-stage leaching, achieving an efficiency in the flotation concentration stage higher than 75%. Based on the performed experimental results the flow sheet for processing of the mixed oxide-sulphide copper ore is proposed.
Metals, 2021
The flotation tailings obtained from Bor Copper Mine contain pyrite (FeS2) and chalcopyrite (CuFeS2), these sulfide minerals are known to promote acid mine drainage (AMD) which poses a serious threat to the environment and human health. This study focuses on the treatment of mine tailings to convert the AMD supporting minerals to more stable forms, while simultaneously valorizing the mine tailings. A combination of hydrometallurgical processes of high-pressure oxidative leaching (HPOL), solvent extraction (SX), and electrowinning (EW) were utilized to recover copper from mine tailings which contain about 0.3% Cu content. The HPOL process yielded a high copper leaching rate of 94.4% when water was used as a leaching medium. The copper leaching kinetics were promoted by the generation of sulfuric acid due to pyrite oxidation. It was also confirmed that a low iron concentration (1.4 g/L) and a high copper concentration (44.8 g/L) obtained in the stripped solution resulted in an improve...
Journal of Sustainable Metallurgy, 2021
The imbalance between raw materials of high economic importance and their supply has increased the search for new approaches to obtain valuable elements from mining tailings. In this study, the extraction of copper, zinc, and lead from sulfidic tailing in sulfate–chloride media was investigated. A 33 Box–Behnken design was applied to evaluate three variables over a 4-h testing period: sulfuric acid concentration (0.01–1.0 mol/L H2SO4), sodium chloride (10–60 g/L NaCl), and temperature (20–70 °C). The design showed two optimum working regions: a combination of a high NaCl level, low H2SO4 level, and medium temperature level for lead leaching, while for copper and zinc, a combination of a medium–high H2SO4 level and a high temperature level. The concentration of NaCl had only a slight impact on their leaching. Based on these results, two-stage leaching was performed. The first stage was carried out under an experimental condition that favored the leaching of lead (60 g/L NaCl, 0.01 mo...
Mongolian Journal of Chemistry
This research investigates the extraction of copper from copper-containing leaching residue, which includes 33.45% of copper, 14.14% of iron, 23.87% of sulfur and trace amounts of silver and other elements. Roasting the copper-containing residue under air and oxygen flow convert sulfides into sulfate, followed by water and acid leaching to extract copper. The process parameters, including leaching temperature, sulfuric acid concentration, leaching time, solid-to liquid ratio, and agitation speed, were optimized for both water and acid leaching methods. Results showed that the maximum copper dissolution efficiency was 93.12% with water leaching, and 97.16% with acid leaching. Chemical analysis revealed that the water and acid leaching residue contained 48.13% and 31.64% of iron, respectively. This study provides valuable insights into the process optimization for copper extraction from copper-containing leaching residue, which can inform the development of more efficient and sustaina...
Journal of Hazardous Materials, 2018
Sulfide copper mineral, typically Chalcopyrite (CuFeS 2), is one of the most common minerals for producing metallic copper via the pyrometallurgical process. Generally, flotation tailings are produced as a byproduct of flotation and still consist of un-recovered copper. In addition, it is expected that more tailings will be produced in the coming years due to the increased exploration of low-grade copper ores. Therefore, this research aims to develop a copper recovery process from flotation tailings using high-pressure leaching (HPL) followed by solvent extraction. Over 94.4% copper was dissolved from the sample (CuFeS 2 as main copper mineral) by HPL in a H 2 O media in the presence of pyrite, whereas the iron was co-dissolved with copper according to an equation given as C Cu = 38.40 × C Fe. To avoid co-dissolved iron giving a negative effect on the subsequent process of electrowinning, solvent extraction was conducted on the pregnant leach solution for improving copper concentration. The result showed that 91.3% copper was recovered in a stripped solution and 98.6% iron was removed under the optimal extraction conditions. As a result, 86.2% of copper was recovered from the concentrate of flotation tailings by a proposed HPL-solvent extraction process.
On the Sulphidation of Anthropogenic Copper Raw Materials with Elemental Sulfur
2019
The object of this research refers to the sulphidation of mine tailings from Zhezkazgan concentrating mill (ZhCM) and mixed copper ore deposits of Bozschakol. The initial materials used are analysized by X-ray Diffraction. The sulphidation process is carried out at temperature values ranging from 300oC to 800oC aiming to follow the influence of the heat on the process studied. The results show that the interval of 300oC 400oC is the best. The effect of changing the sulphur mass percentage during the sulphidation process is discussed. The reuse of mine tailings to extract valuable metals and the environmental hazards decrease are also investigated.