H 3+ n PMo 12− n V n O 40-catalyzed selective oxidation of benzoins to benzils or aldehydes and esters by dioxygen (original) (raw)

Journal of Molecular Catalysis A-chemical, 2001

Abstract

... using the heteropolyacid H 3+n PMo 12−n V n O 40 (HPA-2), as a catalyst affording carboxylic acid derivatives in high yields [3]. On the other hand, cyclic ketones in alcohols were oxidatively cleaved in the presence of stoichiometric amount of oxovanadium(V), VO(OEt)Cl 2 and ...

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