Coexistence of chiral hydrophilic and achiral hydrophobic channels in one multi-helical-array metal?organic framework incorporating helical water cluster chains (original) (raw)
Chemical Communications, 2006
Abstract
A novel host-guest metal-organic compound with both chiral hydrophilic and achiral hydrophobic channels has been obtained through the reaction of Cd(II) ion and a versatile asymmetrical ligand of H(4)bptc (H(4)bptc = 1,1'-biphenyl-2,2',3,3'-tetracarboxylic acid) based on hydro(solvo)thermal reactions.
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