Stability of fluorite and titanite in a calc-silicate rock from the Vizianagaram area, Eastern Ghats Belt, India: FLUORITE AND TITANITE STABILITY (original) (raw)
2004, Journal of Metamorphic Geology
In the Vizianagaram area (E 83°29.442′; N 18°5.418′) of the Eastern Ghats Belt, India, a suite of graphite-bearing calc-silicate granulites, veined by syenitic rocks, developed wollastonite-rich veins at 6–7 kbar and > 850 °C. During subsequent near-isobaric cooling wollastonite was replaced by calcite + quartz and a graphic intergrowth of fluorite + quartz ± clinopyroxene. Titanite with variable Al and F contents is present throughout the rock. Combining the compositional variation of titanite and recent experimental data, it is demonstrated that the mineral assemblage, the composition of coexisting fluids and the mobility of Al exert a far greater control on the composition of titanite than pressure, temperature or the whole rock composition. Thermodynamically computed isothermal–isobaric logfO2– logfCO2 and logfF2– logfO2 grids in the systems Ca–Fe–Si–O–F (CISOF; calcite-free) and Ca–Fe–Si–O–F–C–H (CISOFV; calcite-present) demonstrate the influence of bulk rock and fluid compositions on the stability of the fluorite-bearing assemblages in diverse geological environments and resolve the problem of the stability of titanite in fayalite + fluorite-bearing rocks in the Adirondacks. The mineralogy of the studied rocks and the topological constraints tightly fix the logfO2, logfF2 and logfCO2 at −15.8, −30.6 and 4.1, respectively, at 6.5 kbar and c. 730 °C. Because of the similarity in the P–T conditions, the compositions of pore fluids in the fluorite-bearing assemblages of the Adirondacks and the Eastern Ghats Belt have been compared.
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