Effects of Dopant Ions on the Properties of Polyaniline Conducting Polymer (original) (raw)
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Conductive polymer as Polyaniline (PANI-ES) prepared by chemical oxidation polymerization method at room temperature and studied the effect the dopant sulfuric acid on the structure of the polymer, which prepared with molarity of sulfuric acid (1M), the changes taking place were follow-up by the following measurements: FESEM, FT-IR, I-V character. The diagnosis of the output polymer films by using infrared spectroscopy FT-IR, for doped samples with 1M of sulfuric acid observed change in the intensity of emission opposite the wave number corresponding to each bond, while not noticed any change in the position of the bonds with appearance anew peak return to SO 4 compound. By the FESEM properties of the surface study using the topography FESEM (Field Emission Scanning Electronic Microscopic) and calculated the particle revealed, that the compound has micro granular affected with the presence of acid. Electrical characteristic study by using the two-probe manner, it found that the samples had ohmic plots in which high linear coefficients. The doped samples of polymer had a highest conductivity of 2.98x10-4 S.cm-1 at 383 K, which observed for the H 2 SO 4 doped sample, which shows that was more prominent of localized salt in polymer.
The effect of hydrochloric acid-doped polyaniline to enhance the conductivity
IOP Conference Series: Materials Science and Engineering, 2019
The studies of polyaniline (PANI) and other conducting polymers have shown that they possess semiconducting-properties. PANI is one of the conductive polymers used as a battery electrode, corrosion inhibitor, and sensor. The study aims to investigate the effect of hydrochloric acid dope to PANI. Polyaniline was synthesised by the oxidation of aniline with ammonium peroxidisulphate (APS) as an oxidant by the interfacial method in an immiscible organic/aqueous biphasic system, with hydrochloric acid as a dopant. The result showed that, PANI has conductivities in the range of 3.00.10-2-7.00.10-2 S.cm-1. The morphology and molecular structure of PANI were characterised by scanning electron microscopy (SEM), and FTIR respectively.
Polyaniline. Preparation of a conducting polymer(IUPAC Technical Report)
Pure and Applied Chemistry, 2002
Eight persons from five institutions in different countries carried out polymerizations of aniline following the same preparation protocol. In a "standard" procedure, aniline hydrochloride was oxidized with ammonium peroxydisulfate in aqueous medium at ambient temperature. The yield of polyaniline was higher than 90 % in all cases. The electrical conductivity of polyaniline hydrochloride thus prepared was 4.4 ± 1.7 S cm-1 (average of 59 samples), measured at room temperature. A product with defined electrical properties could be obtained in various laboratories by following the same synthetic procedure. The influence of reduced reaction temperature and increased acidity of the polymerization medium on polyaniline conductivity were also addressed. The conductivity changes occurring during the storage of polyaniline were monitored. The density of polyaniline hydrochloride was 1.329 g cm-3. The average conductivity of corresponding polyaniline bases was 1.4 x108 S cm-1, the ...
Synthesis and Characterization of Polyaniline Based Conducting Polymers
Present work deals with the synthesis of Polyaniline, polynitro aniline, poly m-toludine and poly o-toludine polymers by chemical oxidation method using ammonium per sulfate as chemical oxidant. The yield of all polymers was higher than 90%.The synthesized polymeric material have been characterized by FTIR spectroscopy. FTIR and SEM studies of polymer show the structural and slight morphological changes with change in substituent in monomer units
Polyaniline Conducting Electroactive Polymers Thermal and Environmental Stability Studies
E-Journal of Chemistry, 2006
In the current studies, polyaniline (PANi) was prepared both chemical and electrochemically in the presence of different bronsted acids from aqueous solutions. The effect of thermal treatment on electrical conductivity, and thermal stability of the PANi conducting polymers were investigated using 4-point probe and TGA techniques respectively. It was found that polymer prepared by CV method is more thermally stable than those prepared by the other electrochemical techniques. In this paper we have also reviewed some fundamental information about synthesis, general properties, diverse applications, thermal and environmental stability of polyaniline conducting polymers.
Morphology and electrical properties of hybrid and sulphonated oxalic acid-doped polyaniline
Synthetic Metals, 2010
Polyaniline-polyethylene glycol2000 (PAni-PEG2000) hybrid and sulphonated polyaniline (SPAni) were prepared using oxalic acid as dopant and potassium permanganate as oxidant. The properties of these two conductive polymers were studied in comparison with pure polyaniline (PAni) prepared using the same conditions. The investigated polymers were characterized using FTIR, UV-vis, TGA, TEM, SEM, XRD and their electrical conductivities were also investigated. The morphology of pure polymer was found to be flat ribbon-like form, while presence of polyethylene glycol led to the formation of separate nanospheres. The three polymer samples have different degrees of crystallinity, the highest degree is for SPAni. Unexpectedly, electrical conductivity is in the order SPAni > PAni-PEG2000 > PAni, aging of PAni increases gradually the conductivity of the polymer from 0.0056 to 0.023 S cm −1 and the increase of temperature gradually decreases the conductivity.
Study of the Electrical Characteristics of Polyaniline Prepeared by Electrochemical Polymerization
Energy Procedia, 2012
Polyaniline (PAni) is one of imported polymer for synthesis solar cells .The quality of film depended on the method of polymerization. In this research PAni have been prepared by the electrochemical polymerization of aniline on stainless steel electrode. The electrical conductivity of these films was measured by two-probe method .The electrical conductivity is influenced by preparation conduction such as concentration of H 2 SO 4 and current density .The conductivity between (0.1 -10 -10 ) S/cm depends on PH and current density . The best electrical conductivity about (0.1) S/cm was found PH at (4.2) and current density 0.3mA/cm2.
Synthesis and Characterization of Polyaniline Based Conducting Polymers line
Present work deals with the synthesis of Polyaniline, polynitro aniline, poly m-toludine and poly o-toludine polymers by chemical oxidation method using ammonium per sulfate as chemical oxidant. The yield of all polymers was higher than 90%.The synthesized polymeric material have been characterized by FTIR spectroscopy. FTIR and SEM studies of polymer show the structural and slight morphological changes with change in substituent in monomer units.
Journal of Applied Polymer Science, 2013
The electrical conductivity and yield of polyaniline (PANi) were optimized using a design of experiments (DOE). PANi samples were synthesized by the chemical oxidative polymerization of aniline using methane sulfonic acid as the dopant acid and ammonium persulfate as the oxidant. The main factors in the synthesis of PANi that can affect the conductivity were identified as (i) the concentration of dopant acid, (ii) oxidant-to-monomer ratio, and (iii) the addition rate of oxidant to monomer. Using a Box-Behnken DOE method the regression equation, main effects plots, contour plots, and optimization plots for conductivity and yield were generated and analyzed. Under the optimized conditions of dopant acid concentration of 0.9M, an oxidant addition rate of 30 mL/h and an OM ratio of 0.9, PANi with a conductivity of 1.95 S/cm and yield of 95% was obtained. The observed trends in the four-point probe conductivity measurements were correlated with the polymer structure using fourier transform infrared spectroscopy, X-ray diffraction studies, and scanning electron microscopy.