Chemical-Kinetic Characterization of Autoignition and Combustion of Surrogate Diesel (original) (raw)

A comprehensive investigation was conducted to elucidate the chemical-kinetic mechanisms of toluene combustion relevant to Diesel fuel systems, focusing on both premixed and nonpremixed conditions. Utilizing a detailed kinetic mechanism developed at Lawrence Livermore National Laboratory, numerical simulations were compared with experimental data, revealing discrepancies in reactivity predictions. The study emphasizes the role of aromatic components, particularly toluene, and establishes a foundational understanding of the conditions influencing autoignition and combustion dynamics in Diesel applications.