Photophysical properties and computational investigations of tricarbonylrhenium (I)[2-(4-methylpyridin-2-yl) benzo [d]-X-azole] L and tricarbonylrhenium (I)[2-(benzo [d … (original) (raw)

Journal of …, 2007

Abstract

We report a combined experimental and computational study of new rhenium tricarbonyl complexes based on the bidentate heterocyclic N–N ligands 2-(4-methylpyridin-2-yl)benzo[d]-X-azole (X=N–CH3, O, or S) and 2-(benzo[d]-X-azol-2-yl)-4-methylquinoline (X=N–CH3, O, or S). Two sets of complexes are reported. Chloro complexes, described by the general formula Re(CO)3[2-(4-methylpyridin-2-yl)benzo[d]-X-azole]Cl (X=N–CH3, 1; X=O, 2; X=S, 3) and Re(CO)3[2-(benzo[d]-X-azol-2-yl)-4-methylquinoline]Cl (X=N–CH3, 4; X=O, 5; X=S, 6) were

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