A Model System to Study the Precipitation and Migration of Colloidal Particles in Porous Media (original) (raw)

1996, Journal of Colloid and Interface Science

these fines lead to severe changes in the permeability of Studies on the formation and migration of colloidal iron sulfide the porous rock that result in a decline of the overall oil in porous media were carried out using consolidated artificial aluproduction. In the petroleum industry this phenomena is mina-kaolin cores sintered at 1500ЊC. The artificial aluminacalled ''formation damage'' (2). kaolin cores were imbibed with a solution containing thioacetam-Despite its importance, there are few studies on the formaide and ferrous ions and heated at 80ЊC to obtain the formation tion and migration of colloidal particles in porous media. of FeS particles. Scanning electron micrographs showed particles Matijevic and co-workers have studied the adhesion of partiless than 1 mm in diameter and aggregates of different sizes covcles to macroscopic flat surfaces and the mechanisms inering the surface of the porous media. Core flooding experiments volved in their removal or mobilization (3, 4). Their results, showed that the migration of the fine FeS particles reduced the permeability of core and the injection of surfactant solutions at however, do not apply to porous rocks. The migration of constant salinity restored the original permeability after the profines in porous media has received attention due, mainly, to duction of the redispersed iron sulfide particles, in some cases. its importance in oil production (5). In most of the studies, ᭧ 1996 Academic Press, Inc. porous rocks, like Berea sandstone (6, 7), already containing particles have been used and the results are usually interpreted in terms of colloidal forces, assuming a particular composition for both the porous media and the particles. Another 1

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Straining and Attachment of Colloids in Physically Heterogeneous Porous Media

Vadose Zone Journal, 2004

Colloid transport studies were conducted in water-saturated physicesses that control colloid transport and fate in the subcally heterogeneous systems to gain insight into the processes controlling transport in natural aquifer and vadose zone (variably saturated) surface, including sedimentation , hysystems. Stable monodispersed colloids (carboxyl latex microspheres) drodynamics (Wang et al., 1981;, ionic and porous media (Ottawa quartz sands) that are negatively charged

Properties of Water-Dispersible Colloids from Macropore Deposits and Bulk Horizons of an Agrudalf

Soil Science Society of America Journal, 2004

In the vadose zone, the majority of colloids are associated in aggregates and released following aggregate Mobility of colloids depends in part on the release from aggregates breakdown . Physical-chemical and the stability in suspension. This study determined the soil dispersibility of the different horizons in a Typic Agrudalf. Water-dispersible dispersion is the ultimate state of breakdown that results colloids (WDC) from bulk horizons and macropore deposits were in release of colloids as a consequence of expanding characterized for mineralogy and physical chemical properties. The double layers and dominating repulsive forces as deeffect of solution pH and ionic strength on -potential and flocculation scribed by the DLVO theory (Derjaguin and Landau, behavior was evaluated using dynamic light scattering, and the role 1948; Verwey and Overbeek, 1948). It is generally recogof colloid associated organic C (OC) and sesquioxides were elucidated.

Relative Insignificance of Mineral Grain Zeta Potential to Colloid Transport in Geochemically Heterogeneous Porous Media

Environmental Science & Technology, 2000

The role of -(zeta)potential of mineral grains in the initial deposition kinetics of colloidal particles in geochemically heterogeneous porous media is investigated. Colloid deposition experiments with colloidal silica particles flowing through columns packed with chemically heterogeneous sand were carried out. Patchwise chemical heterogeneity was introduced to the granular porous medium by modifying the surface chemistry of a fraction of the quartz sand grains via reaction with aminosilane. Experimental initial colloid deposition rates and resulting collision efficiencies were compared to theoretical predictions based on the measured average -potential of the chemically heterogeneous sand. It is shown that colloid deposition kinetics are controlled by the degree of patchwise chemical heterogeneity and that use of the measured -potential of the granular porous medium in theoretical predictions leads to erroneous results.

Colloid release and transport processes in natural and model porous media

Colloids and Surfaces A-physicochemical and Engineering Aspects, 1996

Colloid release was observed from packed columns for two natural porous media (sands) and one model system (glass beads with deposited latex colloids). Colloid release was found to occur in all cases when the ionic strength was reduced in columns that were in equilibrium with Na+ ions. Most of the released colloids from the natural porous media were smaller than

Colloid Transport in Geochemically Heterogeneous Porous Media: Modeling and Measurements

Environmental Science & Technology, 1996

To examine colloid transport in geochemically heterogeneous porous media at a scale comparable to field experiments, we monitored the migration of silica-coated zirconia colloids in a two-dimensional layered porous media containing sand coated to three different extents by ferric oxyhydroxides. Transport of the colloids was measured over 1.65 m and 95 days. Colloid transport was modeled by an advection -dispersion -deposition equation incorporating geochemical heterogeneity and colloid deposition dynamics (blocking). Geochemical heterogeneity was represented as favorable (ferric oxyhydroxide-coated) and unfavorable (uncoated sand) deposition surface areas. Blocking was modeled as random sequential adsorption (RSA). Release of deposited colloids was negligible. The time to colloid breakthrough after the onset of blocking increased with increasing ferric oxyhydroxide-coated surface area. As the ferric oxyhydroxide surface area increased, the concentration of colloids in the breakthrough decreased. Model-fits to the experimental data were made by inverse solutions to determine the fraction of surface area favorable for deposition and the deposition rate coefficients for the favorable (ferric oxyhydroxidecoated) and unfavorable sites. The favorable deposition rate coefficient was also calculated by colloid filtration theory. The model described the time to colloid breakthrough and the blocking effect reasonably well and estimated the favorable surface area fraction very well for the two layers with more than 1% ferric oxyhydroxide coating. If mica edges in the uncoated sand were considered as favorable surface area in addition to the ferric oxyhydroxide coatings, the model 0169-7722/02/$ -see front matter D (J.N. Ryan). www.elsevier.com/locate/jconhyd Journal of Contaminant Hydrology 65 (2003) 161 -182

Fines migration in porous media

AIChE Journal, 1987

A model developed by Sharma and Yortsos (1987a) is applied to the processes of fines migration and fines injection in a porous medium. The first is a problem frequently encountered in oil reservoirs when release of fines is triggered by physicochemical interactions of the porous formation with the injected fluids. The second may be a problem in the filtration of relatively large particulates. Simple solutions are provided for both processes by considering size exclusion as the dominant particle retention mechanism. The solutions developed provide expressions for the particle concentration profiles, the open pore density and pore size distribution profiles, as well as the permeability reduction. These expressions are of importance in the evaluation of the extent and depth of formation damage and can be used as designing tools for remedial treatment, such as acidizing or fracturing.

The trapping of colloid particles in porous media: Mechanisms and applications, review

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