Phase-field modelling of microstructural evolution in primary crystallization (original) (raw)

2015

Abstract

One of the main routes to obtain nanostructured materials is through the primary crystallization of metallic glasses. In such transformations, crystallites with a different composition than the amorphous precursor grow with a diffusion-controlled regime. Particle growth is slowed and eventually halted by the impingement between the concentration gradients of surrounding particles. Primary crystallization kinetics is not well described by the KJMA equation, and this fact was generally ascribed to both the soft-impingement effect and the non-random nucleation. However, recent phase-field simulations showed that the underlying physical reason is the change in the local diffusion properties of the amorphous precursor due to the variation of the composition during the transformation. The kinetics of primary crystallization is thus well described by considering a diffusion coefficient of the slowest diffusing species dependent on the local concentration. The nanostructure developed in suc...

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